Oxygen surface exchange in mixed ionic electronic conductor membranes

被引：60
|
作者：
Kim, S
Yang, YL
Jacobson, AJ
Abeles, B
机构：
[1] Univ Houston, Dept Chem, Houston, TX 77204 USA
[2] Univ Houston, Mat Res Sci & Engn Ctr, Houston, TX 77204 USA
来源：
SOLID STATE IONICS | 1999年 / 121卷 / 1-4期
基金：
美国国家科学基金会;
关键词：
oxygen surface exchange coefficients; net surface exchange flux; gas-MIEC interfaces;
D O I：
10.1016/S0167-2738(98)00389-0
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We discuss the different oxygen surface exchange coefficients and the net surface exchange flux i = c(i)k(i0)[exp(n mu(8)/RT) - exp(2n mu/RT)] at gas-MIEC oxide interfaces, where k(i) = k(i0)(p/p(0))(n) is the surface exchange coefficient, derived from isotope exchange experiments, p is the oxygen pressure, mu(s) and mu are the chemical potentials of the gas and of the ion-electron hole pairs at the interface and c(i) is the oxygen ion concentration. The model is applied to oxygen permeation in planar and tubular membranes. (C) 1999 Published by Elsevier Science B.V. All rights reserved.
引用
收藏
页码：31 / 36
页数：6
相关论文
共 50 条
  • [21] Mixed ionic-electronic conducting (MIEC) ceramic-based membranes for oxygen separation
    Sunarso, J.
    Baumann, S.
    Serra, J. M.
    Meulenberg, W. A.
    Liu, S.
    Lin, Y. S.
    da Costa, J. C. Diniz
    JOURNAL OF MEMBRANE SCIENCE, 2008, 320 (1-2) : 13 - 41
  • [22] Effect of plasma atmosphere on the oxygen transport of mixed ionic and electronic conducting hollow fiber membranes
    Buck, F.
    Wiegers, K.
    Schulz, A.
    Schiestel, T.
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2021, 104 : 1 - 7
  • [23] Fluid dynamic modeling of oxygen permeation through mixed ionic-electronic conducting membranes
    Gozalvez-Zafrilla, J. M.
    Santafe-Moros, A.
    Escolastico, S.
    Serra, J. M.
    JOURNAL OF MEMBRANE SCIENCE, 2011, 378 (1-2) : 290 - 300
  • [24] EXCHANGE DIFFUSION IN ONE DIMENSION - LIQUID ELECTROLYTES AND MIXED CONDUCTOR MEMBRANES
    BUCK, RP
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 243 (02): : 279 - 292
  • [25] Mixed Ionic and Electronic Conductor for Li-Metal Anode Protection
    Yan, Jianhua
    Yu, Jianyong
    Ding, Bin
    ADVANCED MATERIALS, 2018, 30 (07)
  • [26] Competition between bulk and surface pathways in mixed ionic electronic conducting oxygen electrodes
    Coffey, GW
    Pederson, LR
    Rieke, PC
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (08) : A1139 - A1151
  • [27] Surface enhancement of oxygen exchange and diffusion in the ionic conductor La2Mo2O9
    Liu, J.
    Chater, R. J.
    Hagenhoff, B.
    Morris, R. J. H.
    Skinner, S. J.
    SOLID STATE IONICS, 2010, 181 (17-18) : 812 - 818
  • [28] Theory of the electrostatic surface potential and intrinsic dipole moments at the mixed ionic electronic conductor (MIEC)-gas interface
    Williams, Nicholas J.
    Seymour, Ieuan D.
    Leah, Robert T.
    Mukerjee, Subhasish
    Selby, Mark
    Skinner, Stephen J.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2021, 23 (27) : 14569 - +
  • [29] Stabilization of Low-Temperature Degradation in Mixed Ionic and Electronic Conducting Perovskite Oxygen Permeation Membranes
    Liu, Yan
    Zhu, Xuefeng
    Li, Mingrun
    Liu, Huanyin
    Cong, You
    Yang, Weishen
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (11) : 3232 - 3236
  • [30] Fundamental modeling and experimental validation of hydrogen and oxygen transport through mixed ionic and electronic conducting membranes
    Kalyanaraman, Jayashree
    Morejudo, Selene H.
    Kjolseth, Christian
    Beeaff, Dustin
    Vigen, Camilla
    Johnson, J. R.
    McCool, Benjamin A.
    JOURNAL OF MEMBRANE SCIENCE, 2022, 660
12345