Synthesis, characterization, and molecular structures of Ni(II) and Cd(II) complexes derived from dithiophosphonate

被引：5
|
作者：
Banaei, Alireza [1 ]
Saadat, Afshin [2 ]
Goli, Mina Mohammad [1 ]
McArdle, Patrick [3 ]
Pourbasheer, Eslam [1 ]
Pargolghasemi, Parinaz [1 ]
机构：
[1] Payame Noor Univ, Dept Chem, Tehran, Iran
[2] Islamic Azad Univ, Dept Chem, Germi Branch, Germi, Iran
[3] NUI Galway, Dept Chem, Galway, Ireland
来源：
HETEROATOM CHEMISTRY | 2016年 / 27卷 / 06期
关键词：
ORGANOPHOSPHORUS COMPOUNDS; METAL-COMPLEXES; CRYSTAL; 2,4-BIS(4-METHOXYPHENYL)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE; NICKEL(II); PATTERNS; ROUTE;
D O I：
10.1002/hc.21345
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two novel dithiophosphonate ligands, HS2P(p-C6H4OMe)(OCH2CH2CH(CH3)(2)) (1) and HS2P(p-C6H4OMe)(OCH(CH3)(2)) (2), were synthesized and characterized by multinuclear (H-1, P-31, and C-13) NMR, infrared spectroscopy as well as elemental analysis. The reactions of 1 and 2 with NiCl(2)6H(2)O and Cd(NO3)(2)4H(2)O in methanol led to novel complexes 3 and 4. The single crystal X-ray structures of 3 and 4 showed tetracoordinated structure with square planar geometry for the nickel complex, while it showed pentacoordinated structure with distorted square-pyramid environment for the cadmium complex.
引用
收藏
页码：353 / 360
页数：8
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