Physico-chemical study of the complex formation between 2-(tosylamino)benzaldehyde bishydrazones and transition metal ions

被引：3

作者：

Popov, L. D. ^{[1
]}

Tupolova, Yu. P. ^{[1
]}

Levchenkov, S. I. ^{[2
]}

Tsaturyan, A. A. ^{[1
]}

Lukov, V. V. ^{[1
]}

Borodkin, S. A. ^{[1
]}

Shcherbakov, I. N. ^{[1
]}

Burlov, A. S. ^{[3
]}

Zubenko, A. A. ^{[4
]}

Pankov, I. V. ^{[1
]}

机构：

[1] Southern Fed Univ, Rostov Na Donu 344090, Russia

[2] Russian Acad Sci, Southern Sci Ctr, Rostov Na Donu, Russia

[3] Southern Fed Univ, Res Inst Phys & Organ Chem, Rostov Na Donu 344090, Russia

[4] North Caucasian Zonal Res Vet Inst, Novocherkassk, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2015年 / 85卷 / 08期

关键词：

bishydrazone; quantum-chemical simulation; coordination compound; magnetochemistry; DINUCLEAR COPPER(II) COMPLEXES; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURE; CIS-DIOXOMOLYBDENUM(VI) COMPLEXES; SCHIFF-BASE; EXCHANGE; COBALT(II); CARBOHYDRAZIDE; LIGANDS; SALICYLALDEHYDE;

D O I：

10.1134/S1070363215080186

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New 2-(tosylamino)benzaldehyde bishydrazones and their complexes with copper(II) and zinc(II) have been synthesized. Structure and properties of the prepared compounds have been studied by means of IR and H-1 NMR spectroscopy as well as magnetochemistry. Quantum-chemical simulation of the relative stability of tautomeric forms of the bishydrazones has been performed.

引用

页码：1902 / 1909

页数：8

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