Physico-chemical study of the complex formation between 2-(tosylamino)benzaldehyde bishydrazones and transition metal ions

被引：3
|
作者：
Popov, L. D. [1 ]
Tupolova, Yu. P. [1 ]
Levchenkov, S. I. [2 ]
Tsaturyan, A. A. [1 ]
Lukov, V. V. [1 ]
Borodkin, S. A. [1 ]
Shcherbakov, I. N. [1 ]
Burlov, A. S. [3 ]
Zubenko, A. A. [4 ]
Pankov, I. V. [1 ]
机构：
[1] Southern Fed Univ, Rostov Na Donu 344090, Russia
[2] Russian Acad Sci, Southern Sci Ctr, Rostov Na Donu, Russia
[3] Southern Fed Univ, Res Inst Phys & Organ Chem, Rostov Na Donu 344090, Russia
[4] North Caucasian Zonal Res Vet Inst, Novocherkassk, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2015年 / 85卷 / 08期
关键词：
bishydrazone; quantum-chemical simulation; coordination compound; magnetochemistry; DINUCLEAR COPPER(II) COMPLEXES; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURE; CIS-DIOXOMOLYBDENUM(VI) COMPLEXES; SCHIFF-BASE; EXCHANGE; COBALT(II); CARBOHYDRAZIDE; LIGANDS; SALICYLALDEHYDE;
D O I：
10.1134/S1070363215080186
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New 2-(tosylamino)benzaldehyde bishydrazones and their complexes with copper(II) and zinc(II) have been synthesized. Structure and properties of the prepared compounds have been studied by means of IR and H-1 NMR spectroscopy as well as magnetochemistry. Quantum-chemical simulation of the relative stability of tautomeric forms of the bishydrazones has been performed.
引用
收藏
页码：1902 / 1909
页数：8
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