Mapping the kinetic events in a linear two-step irreversible-reversible reaction mechanism

被引:13
|
作者
Branco, Daniel P. [1 ]
Yablonsky, Gregory S. [2 ]
Marin, Guy B. [3 ]
Constales, Denis [1 ]
机构
[1] Univ Ghent, Dept Math Anal, Galglaan 2, B-9000 Ghent, Belgium
[2] St Louis Univ, Pk Coll Engn Aviat & Technol, 3450 Lindell Blvd, St Louis, MO 63103 USA
[3] Univ Ghent, Chem Technol Lab, Technol Pk 914, B-9052 Ghent, Belgium
关键词
Kinetic events; Joint kinetics; Map of events; Intersections; Coincidences; Two-step mechanism; THERMODYNAMIC TIME-INVARIANCES; COINCIDENCES; INTERSECTIONS;
D O I
10.1016/j.ces.2016.10.032
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Kinetic events (intersections, maxima and coincidences) are mapped in the batch reactor (BR) and the continuously stirred-tank reactor (CSTR). The mechanism A -> B reversible arrow C was used as an example. A two-stage study was performed: the analysis of single kinetic events, and the ordering by pairs (coincidences) of these events. As a result, all maps of kinetic events were constructed in barycentric parametric coordinates of kinetic constants. A series of analytical expressions between kinetic coefficients and time characteristics of the events were found, in particular a relationship between the intersection times and the kinetic coefficients.
引用
收藏
页码:370 / 380
页数:11
相关论文
共 50 条
  • [21] Kinetic study on in-situ and cooling char combustion in a two-step reaction analyzer
    Fang, Yuan
    Luo, Guangqian
    Li, Jin
    Li, Kaidi
    Chen, Chao
    Zhao, Hong
    Duan, Ran
    Yao, Hong
    PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2017, 36 (02) : 2147 - 2154
  • [22] Two-Step Optimization of Linear Distributed Arrays
    Ellison, Sean M.
    Nanzer, Jeffery A.
    2018 IEEE ANTENNAS AND PROPAGATION SOCIETY INTERNATIONAL SYMPOSIUM ON ANTENNAS AND PROPAGATION & USNC/URSI NATIONAL RADIO SCIENCE MEETING, 2018, : 2111 - 2112
  • [23] Two-Step Dynamic Encoding for Linear Decompressors
    Gizdarski, Emil
    2014 IEEE 23RD ASIAN TEST SYMPOSIUM (ATS), 2014, : 330 - 335
  • [24] Non-linear impedance for a two-step electrode reaction with an intermediate adsorbed species
    Diard, JP
    LeGorrec, B
    Montella, C
    ELECTROCHIMICA ACTA, 1997, 42 (07) : 1053 - 1072
  • [25] Macrocycle Unidirectional Transport Along a Linear Molecule by a Two-Step Chemical Reaction Sequence
    Catalan, Aldo C.
    Pena-Zarate, Lucio
    Cervantes, Ruy
    Vela, Alberto
    Tiburcio, Jorge
    CHEMISTRYOPEN, 2025, 14 (01):
  • [26] Non-linear impedance for a two-step electrode reaction with an intermediate adsorbed species
    Ecole Nationale Superieure, d'Electrochimie et, d'Electrometallurgie de Grenoble, Saint Martin d'Heres, France
    Electrochim Acta, 7 (1053-1072):
  • [27] Kinetic Model for Two-Step Nucleation of Peptide Assembly
    Hsieh, Ming-Chien
    Lynn, David G.
    Grover, Martha A.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2017, 121 (31): : 7401 - 7411
  • [28] Two-step kinetics of As/P exchange reaction
    Suh, KY
    Lee, HH
    Yoon, E
    JOURNAL OF APPLIED PHYSICS, 1999, 85 (01) : 233 - 236
  • [29] Optimization for two-step biochemical kinetic resolution of enantiomers
    Zhu, SD
    Wu, YX
    Yu, ZN
    BIOCATALYSIS AND BIOTRANSFORMATION, 2005, 23 (02) : 97 - 101
  • [30] A two-step reaction sequence for the syntheses of tetrahydronaphthalenes
    Hilt, G
    Luers, S
    Smolko, KI
    ORGANIC LETTERS, 2005, 7 (02) : 251 - 253