Photoemission study of the Sm/Si(100)2x1 interface

被引:0
|
作者
Xu, SH
Lu, ED
Yu, XJ
Pan, HB
Zhang, FP
Xu, PS
机构
[1] Natl. Synchrt. Radiation Laboratory, Univ. of Sci. and Technol. of China, Hefei
关键词
D O I
10.1016/0368-2048(96)02953-2
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
The behavior of interface formed by growing thin Sm film on the Si(100)2x1 substrate at room temperature and its temperature evolution has been investigated by core-level and valence-band photoemission using synchrotron radiation. The experimental results show the existence of distinct stages corresponding to chemisorption and agglomeration of Sm atoms(coverage theta<0.5ML), reactive interdiffusion(0.5<theta<4-6ML), and growth of metallic Sm. Compared to Si(111)7x7 the reactivity of Sm on the Si(100)2x1 substrate is enhanced and a greater tendency for interdiffusion of Sm and Si is observed. Like on Si(111), a multiphase interface is formed but less stable. After being annealed, this phase disappears gradually. When the annealing temperature gets up to 1000 degrees C, an original 2x1 LEED patterns appear again on the surface. Together with a model, the interface formation and the interface profile is discussed in detail in the text.
引用
收藏
页码:189 / 192
页数:4
相关论文
共 50 条
  • [21] FREEZING OF THE 2X1 STRUCTURE AT COMMENSURATE AG(100)-SI(100) INTERFACE
    KIMURA, Y
    TAKAYANAGI, K
    SURFACE SCIENCE, 1992, 276 (1-3) : 166 - 173
  • [22] STRUCTURE OF THE NA/SI(100)2X1 AND CS/SI(100)2X1 INTERFACES INVESTIGATED BY PHOTOEMISSION EXTENDED X-RAY-ABSORPTION FINE-STRUCTURE
    KIM, ST
    SOUKIASSIAN, P
    BARBIER, L
    KAPOOR, S
    HURYCH, Z
    PHYSICAL REVIEW B, 1991, 44 (11): : 5622 - 5628
  • [23] CHARGE-TRANSFER ACROSS THE AS/SI(100)-2X1 INTERFACE
    EVANS, JA
    LAINE, AD
    WEIGHTMAN, P
    MATTHEW, JAD
    WOOLF, DA
    WESTWOOD, DI
    WILLIAMS, RH
    PHYSICAL REVIEW B, 1992, 46 (03): : 1513 - 1520
  • [24] High-resolution photoemission study of acetylene adsorption and reaction with the Si(100)-2x1 surface
    Xu, SH
    Yang, Y
    Keeffe, M
    Lapeyre, GJ
    Rotenberg, E
    PHYSICAL REVIEW B, 1999, 60 (16) : 11586 - 11592
  • [25] SI INDIFFUSION ON GE(100)-(2X1) STUDIED BY CORE-LEVEL PHOTOEMISSION
    LIN, DS
    MILLER, T
    CHIANG, TC
    PHYSICAL REVIEW B, 1992, 45 (19): : 11415 - 11418
  • [26] Interaction of Lewis Acids with Si(100)-2x1 and Ge(100)-2x1 Surfaces
    Ferguson, Glen Allen
    Das, Ujjal
    Raghavachari, Krishnan
    JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (23): : 10146 - 10150
  • [27] SURFACE INFRARED STUDY OF SI(100)-(2X1)H
    CHABAL, YJ
    RAGHAVACHARI, K
    PHYSICAL REVIEW LETTERS, 1984, 53 (03) : 282 - 285
  • [28] Si2H6 Dissociative Chemisorption and Dissociation on Si(100)-(2x1) and Ge(100)-(2x1)
    Veyan, Jean-Francois
    Choi, Heesung
    Huang, Min
    Longo, R. C.
    Ballard, Josh B.
    McDonnell, Stephen
    Nadesalingam, Manori P.
    Dong, Hong
    Chopra, Irinder S.
    Owen, James H. G.
    Kirk, Wiley P.
    Randall, John N.
    Wallace, Robert M.
    Cho, Kyeongjae
    Chabal, Yves J.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (50): : 24534 - 24548
  • [29] PHOTOEMISSION-STUDY OF THE SURFACE-STATES THAT PIN THE FERMI LEVEL AT SI(100)2X1 SURFACES
    MARTENSSON, P
    CRICENTI, A
    HANSSON, GV
    PHYSICAL REVIEW B, 1986, 33 (12): : 8855 - 8858
  • [30] Angle-resolved photoemission study of the β-SiC(100)-(2x1)-surface
    Husken, H
    Schroter, B
    Richter, W
    Kackell, P
    Bechstedt, F
    SILICON CARBIDE, III-NITRIDES AND RELATED MATERIALS, PTS 1 AND 2, 1998, 264-2 : 383 - 386