Efficient synthesis of manganese(II) carboxylates: from a trinuclear cluster [Mn3(PhCO2)6(THF)4] to a unique [Mn(PhCO2)2]n chiral 3D network

被引：11

作者：

Kornowicz, Arkadiusz ^{[1
]}

Komorski, Szymon ^{[1
]}

Wrobel, Zbigniew ^{[2
]}

Justyniak, Iwona ^{[2
]}

Nedelko, Natalia ^{[3
]}

Slawska-Waniewska, Anna ^{[3
]}

Balawender, Robert ^{[2
]}

Lewinski, Janusz ^{[1
,2
]}

机构：

[1] Warsaw Univ Technol, Fac Chem, PL-00664 Warsaw, Poland

[2] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland

[3] Polish Acad Sci, Inst Phys, PL-02668 Warsaw, Poland

来源：

DALTON TRANSACTIONS | 2014年 / 43卷 / 08期

关键词：

MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURE; COMPLEXES; CHEMISTRY; LIGAND; BASES; WATER;

D O I：

10.1039/c3dt53211a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An efficient synthetic procedure for obtaining manganese carboxylates including a trinuclear cluster [Mn-3(PhCO2)(6)(THF)(4)](2) and a unique [Mn(PhCO2)(2)](n) chiral 3D network is reported. The procedure involves a simple redox process, in which acidic protons are reduced to gaseous hydrogen by oxidizing metallic manganese under solvothermal conditions.

引用

页码：3048 / 3051

页数：4

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