Efficient synthesis of manganese(II) carboxylates: from a trinuclear cluster [Mn3(PhCO2)6(THF)4] to a unique [Mn(PhCO2)2]n chiral 3D network

被引：11
|
作者：
Kornowicz, Arkadiusz [1 ]
Komorski, Szymon [1 ]
Wrobel, Zbigniew [2 ]
Justyniak, Iwona [2 ]
Nedelko, Natalia [3 ]
Slawska-Waniewska, Anna [3 ]
Balawender, Robert [2 ]
Lewinski, Janusz [1 ,2 ]
机构：
[1] Warsaw Univ Technol, Fac Chem, PL-00664 Warsaw, Poland
[2] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland
[3] Polish Acad Sci, Inst Phys, PL-02668 Warsaw, Poland
来源：
DALTON TRANSACTIONS | 2014年 / 43卷 / 08期
关键词：
MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURE; COMPLEXES; CHEMISTRY; LIGAND; BASES; WATER;
D O I：
10.1039/c3dt53211a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An efficient synthetic procedure for obtaining manganese carboxylates including a trinuclear cluster [Mn-3(PhCO2)(6)(THF)(4)](2) and a unique [Mn(PhCO2)(2)](n) chiral 3D network is reported. The procedure involves a simple redox process, in which acidic protons are reduced to gaseous hydrogen by oxidizing metallic manganese under solvothermal conditions.
引用
收藏
页码：3048 / 3051
页数：4
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