Highly sensitive detection of Pb2+ and Cu2+ based on ZIF-67/MWCNT/ Nafion-modified glassy carbon electrode

被引：53
|
作者：
Zhang, Yueying [1 ]
Yu, Hao [1 ]
Liu, Tong [1 ]
Li, Weijia [1 ]
Hao, Xidong [1 ]
Lu, Qi [1 ]
Liang, Xishuang [1 ]
Liu, Fengmin [1 ]
Liu, Fangmeng [1 ]
Wang, Chenguang [1 ]
Yang, Chunhua [2 ]
Zhu, Hongqiu [2 ]
Lu, Geyu [1 ]
机构：
[1] Jilin Univ, State Key Lab Integrated Optoelect, Key Lab Gas Sensors, Coll Elect Sci & Engn, 2699 Qianjin St, Changchun 130012, Peoples R China
[2] Cent South Univ, Sch Informat Sci & Engn, Changsha 410083, Peoples R China
来源：
ANALYTICA CHIMICA ACTA | 2020年 / 1124卷
基金：
国家重点研发计划;
关键词：
Multiphase modification layer; Electrochemical sensor; Heavy metal ion detection; GCE; Voltammetry; METAL-ORGANIC FRAMEWORKS; ELECTROCHEMICAL DETERMINATION; EFFICIENT REMOVAL; HEAVY-METALS; NANOCOMPOSITE; CD(II); PB(II); CU(II); WATER; FABRICATION;
D O I：
10.1016/j.aca.2020.05.023
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A series of different facile modification layers (MLs) was designed to gradually increase the electrochemical sensing performance of glassy carbon electrode (GCE) for simultaneously detecting Pb2+ and Cu2+. ML designs were mainly a different combination of ZIF-67, MWCNT and Nafion, and their different electrochemical sensing performances were investigated by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), square wave stripping voltammetry (SWSV) and chronocoulometry. The fabricated sensor, which modified with ZIF-67/MWCNT and Nafion layer, exhibited the biggest response peak current to Pb2+ and Cu2+. In addition, it displayed a wide linear detection range of 1.38 nM-5 mu M for Pb2+ and 1.26 nM-5 mu M for Cu2+, a detection accuracy of about 1 nM for both Pb2+ and Cu2+, and an excellent stability for both Pb2+ and Cu2+. We also analyzed the real water sample taken from Changchun's Sanjia Lake and Yan Lake. We believe this ML design provides instruction for building highperformance electrochemical sensing systems. (C) 2020 Elsevier B.V. All rights reserved.
引用
收藏
页码：166 / 175
页数：10
相关论文
共 50 条
  • [41] Simultaneously determination of trace Cd2+ and Pb2+ based on L-cysteine/graphene modified glassy carbon electrode
    Zhou, Wenshu
    Li, Caihong
    Sun, Chong
    Yang, Xiaodi
    [J]. FOOD CHEMISTRY, 2016, 192 : 351 - 357
  • [42] Fabrication of amperometric cholesterol biosensor based on SnO2 nanoparticles and Nafion-modified carbon paste electrode
    Gözde Aydoğdu Tığ
    Derya Koyuncu Zeybek
    Şule Pekyardımcı
    [J]. Chemical Papers, 2016, 70 : 695 - 705
  • [43] Simultaneous detection of Pb2+, Cu2+ and Hg2+ by differential pulse voltammetry at an indium tin oxide glass electrode modified by hydroxyapatite
    Sun, Mingxu
    Li, Ziheng
    Wu, Shuang
    Gu, Yuwei
    Li, Yuying
    [J]. ELECTROCHIMICA ACTA, 2018, 283 : 1223 - 1230
  • [44] Fabrication of amperometric cholesterol biosensor based on SnO2 nanoparticles and Nafion-modified carbon paste electrode
    Tig, Gozde Aydogdu
    Zeybek, Derya Koyuncu
    Pekyardimci, Sule
    [J]. CHEMICAL PAPERS, 2016, 70 (06) : 695 - 705
  • [45] PRE-COATED MERCURY FILM ON GLASSY-CARBON ELECTRODE FOR THE SIMULTANEOUS DETERMINATION OF Cu2+, Zn2+, Cd2+, AND Pb2+ IN WATER
    Pei, Jingxuan
    Yu, Xiang
    Liu, Xingju
    Zhang, Chao
    [J]. STUDIA UNIVERSITATIS BABES-BOLYAI CHEMIA, 2019, 64 (03): : 203 - 216
  • [46] Polydiacetylene-based sensor for highly sensitive and selective Pb2+ detection
    Wang, Minwu
    Wang, Fang
    Wang, Yong
    Zhang, Wei
    Chen, Xiaoqiang
    [J]. DYES AND PIGMENTS, 2015, 120 : 307 - 313
  • [47] Determination of Cd2+ and Pb2+ on glassy carbon electrode modified by electrochemical reduction of aromatic diazonium salts
    Fan, Lishuang
    Chen, Jiuan
    Zhu, Shuyun
    Wang, Min
    Xu, Guobao
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (09) : 1823 - 1825
  • [48] Remediation of water using Theobroma Cacao pod-based activated carbon: a novel approach as determined by highly sensitive BiNP/MWCNT/Nafion-modified GCE
    Palisoc, Shirley T.
    Racines, Lotis R.
    Alea, Glenn V.
    Natividad, Michelle T.
    [J]. MATERIALS RESEARCH EXPRESS, 2019, 6 (11)
  • [49] A biocompatible nano TiO2/nafion composite modified glassy carbon electrode for the detection of fenitrothion
    Kumaravel, A.
    Chandrasekaran, M.
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2011, 650 (02) : 163 - 170
  • [50] Azacrown[N,S,O]-modified porphyrin sensor for detection of Ag+, Pb2+, and Cu2+
    Yuting Chen
    Kaili Wang
    [J]. Photochemical & Photobiological Sciences, 2013, 12 : 2001 - 2007
12345