Enantioselective self-assembly of chiral calix[4]arene acid with amines

被引：41
|
作者：
Zheng, Yan-Song [1 ]
Ran, Shu-Yun [1 ]
Hu, Yu-Jian [1 ]
Liu, Xian-Xian [2 ]
机构：
[1] Huazhong Univ Sci & Technol, Dept Chem, Wuhan 430074, Peoples R China
[2] Guilin Normal Coll, Dept Chem, Guilin 541001, Guangxi, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 09期
基金：
中国国家自然科学基金;
关键词：
MOLECULAR RECOGNITION; SOLDIERS PRINCIPLE; RESOLUTION; DERIVATIVES; RECEPTORS; MECHANISMS; NANOTUBES; SYSTEMS; SALT; GEL;
D O I：
10.1039/b817974c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A chiral calix[4] arene bearing L-2,3-dibenzoyltartaric acid groups at the lower rim was synthesized and could enantioselectively self-assemble to result in a gel or suspension only with one enantiomer of chiral amines; as revealed by electron microscopy, the resultant gel was of nanofibers with a high aspect ratio but the suspension was composed of nanospheres.
引用
收藏
页码：1121 / 1123
页数：3
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