Thermodynamic and spectroscopic studies of copper(II) complexes with three bis(amide) ligands derived from L-tartaric acid

被引:19
|
作者
Tounsi, N
Dupont, L
Mohamadou, A
Aplincourt, M
Plantier-Royon, R
Massicot, F
Harakat, D
Portella, C
机构
[1] Univ Reims, GRECI, EA 2067, Fac Sci, F-51687 Reims 2, France
[2] Univ Reims, Lab React Select & Applicat, UMR 6519, CNRS,Fac Sci, F-51687 Reims 2, France
关键词
bis-amide; metal complexes; stability constant; potentiometric study;
D O I
10.1016/j.jinorgbio.2005.09.010
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The interactions of three bis(amide) ligands derived from tartaric acid with copper (II) were investigated in aqueous solution by a combination of potentiometry, UV-vis spectrophotometry, electron paramagnetic resonance (EPR), and mass spectrometry. The formation constants of the complexes were measured and their relative structures were reported. The sites of complexation of these ligands are investigated based mostly on their electronic and EPR spectra and on the comparison with the behaviour of some analog compounds. (c) 2005 Elsevier Inc. All rights reserved.
引用
收藏
页码:2423 / 2435
页数:13
相关论文
共 50 条
  • [41] Synthesis and spectral studies of zinc(II) and palladium(II) complexes of amide ligands derived from 2-aminopyridine
    Garg, BS
    Kumar, V
    Reddy, MJ
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1996, 35 (07): : 598 - 600
  • [42] THE SYNTHESIS AND STRUCTURE OF CHIRAL DI-N-PARA-TOLUENESULFONYL DIAZACORONANDS DERIVED FROM L-TARTARIC ACID
    JURCZAK, J
    OSTASZEWSKI, R
    ANDREETTI, GD
    CALESTANI, G
    HETEROCYCLES, 1990, 31 (03) : 397 - 400
  • [43] Li+-induced selective gelation of discrete homochiral structural isomers derived from L-tartaric acid
    Dubey, Mrigendra
    Kumar, Ashish
    Gupta, Rakesh Kumar
    Pandey, Daya Shankar
    CHEMICAL COMMUNICATIONS, 2014, 50 (60) : 8144 - 8147
  • [44] SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPLEXES WITH QUADRIDENTATE DERIVATIVES OF L-PROLINE AMIDE AND L-PROLINE METHYL AMIDE
    MURAKAMI, T
    HATANO, M
    INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1986, 125 (02): : 111 - 115
  • [45] Synthesis, spectroscopic and thermal studies of bis(pentafluorophenyl)nickel(II) complexes with β-ketoiminate ligands
    Sanchez, G
    Serrano, JL
    Perez, J
    Lopez, G
    JOURNAL OF FLUORINE CHEMISTRY, 1997, 86 (02) : 143 - 147
  • [46] Dimeric versus polymeric coordination in copper(II) cationic complexes with bis(chelating) oxime and amide ligands
    Buvailo, Andrii I.
    Gumienna-Kontecka, Elzbieta
    Pavlova, Svetlana V.
    Fritsky, Igor O.
    Haukka, Matti
    DALTON TRANSACTIONS, 2010, 39 (27) : 6266 - 6275
  • [47] Structural, spectroscopic and electrochemical studies of binuclear nickel(II) complexes of bis(pentadentate) ligands derived from bis(1,4,7-triazacyclononane) macrocycles
    Brudenell, SJ
    Spiccia, L
    Bond, AM
    Mahon, PC
    Hockless, DCR
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (23): : 3919 - 3925
  • [48] Structural, spectroscopic, and electrochemical studies of binuclear manganese(II) complexes of bis(pentadentate) ligands derived from bis(1,4,7-triazacyclononane) macrocycles
    Brudenell, SJ
    Spiccia, L
    Bond, AM
    Fallon, GD
    Hockless, DCR
    Lazarev, G
    Mahon, PJ
    Tiekink, ERT
    INORGANIC CHEMISTRY, 2000, 39 (05) : 881 - 892
  • [49] Growth and Spectroscopic Studies on the L-Tartaric Acid Doped Ammonium Dihydrogen Phosphate Non-Linear Optical Single Crystals
    Arulmani, S.
    Venkatesan, A.
    Rajasaravanan, M. E.
    Senthil, S.
    MATERIALS TODAY-PROCEEDINGS, 2019, 8 : 136 - 141
  • [50] ASYMMETRIC OXIDATION OF OLEFINS WITH OSMIUM-TETROXIDE COORDINATED BY CHIRAL DIAMINES DERIVED FROM L-TARTARIC ACID
    YAMADA, T
    NARASAKA, K
    CHEMISTRY LETTERS, 1986, (01) : 131 - 134