Intergrown Li2FeSiO4•LiFePO4-C nanocomposites as high-capacity cathode materials for lithium-ion batteries

被引:76
|
作者
Gao, Haiyan [1 ]
Hu, Zhe [1 ]
Zhang, Kai [1 ]
Cheng, Fangyi [1 ]
Chen, Jun [1 ]
机构
[1] Nankai Univ, Coll Chem, Minist Educ, Key Lab Adv Energy Mat Chem, Tianjin 300071, Peoples R China
关键词
ELECTROCHEMICAL PERFORMANCE; LIMN2O4; FE; LI2FESIO4; MN;
D O I
10.1039/c3cc40565f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Intergrown Li2FeSiO4 center dot LiFePO4-C nanocomposites with different compositions were synthesized by a tartaric acid assisted sol-gel method. The 0.96Li(2)FeSiO(4)center dot 0.04LiFePO(4)-C nanocomposites exhibited greatly enhanced electrochemical properties, attaining a high discharge capacity up to 284.7 mA h g(-1) (equal to ca. 1.72 Li+ per molecule) at 45 degrees C.
引用
收藏
页码:3040 / 3042
页数:3
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