Metal assisted rearrangement of 2,2′-pyridil with M(ClO4)2•6H2O (M=CoII, NiII and CuII):: syntheses, characterization and crystal structures

被引：25
|
作者：
Du, M
Bu, XH [1 ]
Shionoya, M
Shiro, M
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Univ Tokyo, Grad Sch Sci, Dept Chem, Tokyo 1130033, Japan
[3] Rigaku Corp, Tokyo 1968666, Japan
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2002年 / 607卷 / 2-3期
基金：
中国国家自然科学基金;
关键词：
crystal structure; Co-III; Ni-II and Cu-III complexes; 2,2 '-pyridil; rearrangement;
D O I：
10.1016/S0022-2860(01)00913-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
With the aim of examining the metal-assisted rearrangement behaviors of 2,2'-pyridil (L), its reactions with M(ClO4)(2)(.)6H(2)O (M = Co-II, Ni-II and Cu-II) were considered. X-ray diffraction analyses of the products reveal the formation of complexes containing 2,2'-pyridilate anion (L-1) or picolinate anion (L-2) as arrangement products of 2,2'-pyridil, induced by different metal ions. [Co-III(L-1)(2)](ClO4)(CH3OH)-C-. (1) and [Ni-II(L-1)(2)](.)2H(2)O (2) have similar mononuclear structures, and it should be noted that the Co-II ion is unstable to oxidation in this process. However, [Cu-II(L-2)(2)](.)2H(2)O (3) forms a one-dimensional linear complex via Cu-O weak interactions. (C) 2002 Elsevier Science B.V. All rights reserved.
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页码：155 / 161
页数：7
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