Ascorbic acid as corrosion inhibitor for Q235 mild steel in acidic environments

被引:63
|
作者
Chidiebere, Maduabuchi A. [1 ,2 ]
Oguzie, Emeka E. [2 ]
Liu, Li [1 ]
Li, Ying [1 ]
Wang, Fuhui [1 ]
机构
[1] Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China
[2] Fed Univ Technol, Dept Chem, Electrochem & Mat Sci Res Lab, Pmb 1526, Owerri, Nigeria
关键词
Mild steel; Corrosion; Inhibition; Adsorption; Impedance; Polarization; DENSITY-FUNCTIONAL THEORY; SULFURIC-ACID; ADSORPTION BEHAVIOR; CARBON-STEEL; DERIVATIVES; PERFORMANCE; EXTRACT; SURFACE; DFT; POLARIZATION;
D O I
10.1016/j.jiec.2014.11.029
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The inhibition effect of ascorbic acid (AA) on mild steel corrosion in 1 M HCl and 0.5 M H2SO4 was estimated using electrochemical and surface probe techniques. Potentiodynamic polarization results showed AA to be a mixed type inhibitor in both acidic environments, whereas the impedance results revealed adsorption of the AA species on the steel surface. Atomic force microscopy (AFM) and scanning electron microscopy (SEM) studies revealed the formation of a protective film adsorbed AA on the steel surface. Quantum chemical calculations were used to confirm the ability of AA to adsorb on a steel surface. (C) 2014 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:182 / 192
页数:11
相关论文
共 50 条
  • [41] Short-Term Corrosion Characteristic of Q235 Steel under Different Atmospheric Environments of Hunan
    Xuankai Wang
    Jun Wang
    Xiaobao Zhou
    Yi Xie
    Junjun Chen
    Zhimin Ding
    Tangqing Wu
    Jun Luo
    Fucheng Yin
    Journal of Materials Engineering and Performance, 2022, 31 : 7892 - 7905
  • [42] Short-Term Corrosion Characteristic of Q235 Steel under Different Atmospheric Environments of Hunan
    Wang, Xuankai
    Wang, Jun
    Zhou, Xiaobao
    Xie, Yi
    Chen, Junjun
    Ding, Zhimin
    Wu, Tangqing
    Luo, Jun
    Yin, Fucheng
    JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE, 2022, 31 (10) : 7892 - 7905
  • [43] Study of the Inhibition Mechanism of Imidazoline Derivative Inhibitor on CO2 corrosion for Q235 Steel
    Wang Bin
    Du Min
    Zhang Jing
    MULTI-FUNCTIONAL MATERIALS AND STRUCTURES II, PTS 1 AND 2, 2009, 79-82 : 981 - 984
  • [44] Effect of three penicillin-based as corrosion inhibitors on Q235 steel in hydrochloric acid
    Feng, Li
    Yao, Hailing
    Ma, Xuemei
    Zhu, Hailin
    Hu, Zhiyong
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2023, 18 (12):
  • [45] Corrosion inhibition of ionic liquids on the surface of Q235 steel in methanol/sulfuric acid medium
    Zheng T.
    Wang L.
    Liu J.
    Wang J.
    Liu, Jinyan (liujinyan2007@163.com), 1600, Materials China (71): : 2230 - 2239
  • [46] Corrosion Behavior of 35CrMn and Q235 Steel in Simulated Acid Rain Conditions
    Xiu-li Zuo
    Bin Xiang
    Xing Li
    Zi-dong Wei
    Journal of Materials Engineering and Performance, 2012, 21 : 524 - 529
  • [47] Corrosion inhibition performance of synergistic inhibitors on Q235 steel in methanol/formic acid medium
    Jia Wang
    Jinyan Liu
    Qian Liu
    Yao Chong
    Journal of Materials Science, 2022, 57 : 16025 - 16047
  • [48] Evaluation of the inhibitor effect of L-ascorbic acid on the corrosion of mild steel
    Ferreira, ES
    Giacomelli, C
    Giacomelli, FC
    Spinelli, A
    MATERIALS CHEMISTRY AND PHYSICS, 2004, 83 (01) : 129 - 134
  • [49] Corrosion Behavior of 35CrMn and Q235 Steel in Simulated Acid Rain Conditions
    Zuo, Xiu-li
    Xiang, Bin
    Li, Xing
    Wei, Zi-dong
    JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE, 2012, 21 (04) : 524 - 529
  • [50] Corrosion inhibition performance of synergistic inhibitors on Q235 steel in methanol/formic acid medium
    Wang, Jia
    Liu, Jinyan
    Liu, Qian
    Chong, Yao
    JOURNAL OF MATERIALS SCIENCE, 2022, 57 (33) : 16025 - 16047