Bimetallic Cu/Pt Oxygen Reduction Reaction Catalyst for Fuel Cells Cathode Materials

被引:14
|
作者
Alekseeva, Elena [1 ]
Stelmashuk, Tatyana [1 ]
Danilov, Stepan [1 ]
Yang, Peixia [2 ]
Levin, Oleg [1 ]
机构
[1] St Petersburg State Univ, Inst Chem, St Petersburg 199034, Russia
[2] Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Heilongjiang, Peoples R China
基金
俄罗斯基础研究基金会;
关键词
oxygen reduction reaction; bimetallic catalyst; template synthesis; Cu salen polymer complex; NITROGEN-DOPED GRAPHENE; X-RAY PHOTOELECTRON; PT-CU NANOPARTICLES; ONE-POT SYNTHESIS; BIFUNCTIONAL ELECTROCATALYSTS; METAL-COMPLEXES; EFFICIENT; ALKALINE; SURFACE; NICKEL;
D O I
10.3390/catal10060667
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The oxygen reduction reaction (ORR) is a key process for the operation of fuel cells. To accelerate the sluggish kinetics of ORR, a wide range of catalysts have been proposed and tested. In this work, a nano-dispersed copper-impregnated platinum catalyst prepared by electrodeposition of platinum on a poly[Cu(Salen)] template followed by polymer destruction is described. In addition to the high activity of the thus prepared catalyst in the oxygen reduction reaction surpassing that of both polycrystalline platinum catalyst and the commercial carbon-platinum catalyst ("E-TEK"), it showed remarkable tolerance to the presence of methanol in solution.
引用
收藏
页码:1 / 14
页数:14
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