Poly[[(μ-3,4-dicarboxytetrahydrofuran-2,5-dicarboxylato-k4O1,O2,O5:O2′)(1,10-phenanthroline-k2N,N′)copper(II)]0.69-hydrate]

被引:5
|
作者
Lue, Yuanqi [1 ]
机构
[1] Dezhou Univ, Dept Chem, Dezhou 253023, Peoples R China
关键词
D O I
10.1107/S1600536808027918
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the crystal structure of the title compound, {[Cu(C8H6O9)-(C12H8N2)].0.69H(2)O}(n), the Cu-II atom has a distorted octahedral geometry, coordinated by four O atoms from two 3,4dicarboxytetrahydrofuran- 2,5- dicarboxylate ligands and two N atoms from one 1,10-phenanthroline ligand. One of the carboxylate groups bridges the Cu-II atoms, forming a zigzag chain running along the b axis. The chains are linked by a pi-pi interaction between aromatic rings with a centroid-to-centroid distance of 3.567 (1) angstrom, and by hydrogen bonds between the carboxylate group and the disordered water molecule, forming a three-dimensional network.
引用
收藏
页码:M1245 / U285
页数:12
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