Active Cross-Linkers that Lead to Active Gels

被引：40

作者：

Zhang, Ye ^{[1
]}

Zhou, Ning ^{[1
]}

Akella, Sathish ^{[2
]}

Kuang, Yi ^{[1
]}

Kim, Dongshin ^{[2
]}

Schwartz, Alyssa ^{[1
]}

Bezpalko, Marc ^{[1
]}

Foxman, Bruce M. ^{[1
]}

Fraden, Seth ^{[2
]}

Epstein, Irving R. ^{[1
]}

Xu, Bing ^{[1
]}

机构：

[1] Brandeis Univ, Dept Chem, Waltham, MA 02454 USA

[2] Brandeis Univ, Dept Phys, Waltham, MA 02454 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 44期

基金：

美国国家科学基金会;

关键词：

cross-linkers; gels; polymers; ruthenium; soft materials; BELOUSOV-ZHABOTINSKY REACTION; TRANSITION-METAL-COMPLEXES; MULTIFUNCTIONAL INITIATORS; POLYMERIC MATERIALS; CHEMI-LUMINESCENCE; HYDROGELS; TRIS(2,2'-BIPYRIDINE)RUTHENIUM(II); CHEMILUMINESCENCE; TEMPERATURE; LINKING;

D O I：

10.1002/anie.201304437

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chemomechanical reaction: The first octahedral ruthenium bipyridine complex that bears six polymerizable vinyl groups is used as an active cross-linker (see scheme, left). It is a key building block for cross-linked polymeric networks (right) thus allowing the construction of molecular architectures in chemomechanical soft materials. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：11494 / 11498

页数：5

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