Active Cross-Linkers that Lead to Active Gels

被引:40
|
作者
Zhang, Ye [1 ]
Zhou, Ning [1 ]
Akella, Sathish [2 ]
Kuang, Yi [1 ]
Kim, Dongshin [2 ]
Schwartz, Alyssa [1 ]
Bezpalko, Marc [1 ]
Foxman, Bruce M. [1 ]
Fraden, Seth [2 ]
Epstein, Irving R. [1 ]
Xu, Bing [1 ]
机构
[1] Brandeis Univ, Dept Chem, Waltham, MA 02454 USA
[2] Brandeis Univ, Dept Phys, Waltham, MA 02454 USA
基金
美国国家科学基金会;
关键词
cross-linkers; gels; polymers; ruthenium; soft materials; BELOUSOV-ZHABOTINSKY REACTION; TRANSITION-METAL-COMPLEXES; MULTIFUNCTIONAL INITIATORS; POLYMERIC MATERIALS; CHEMI-LUMINESCENCE; HYDROGELS; TRIS(2,2'-BIPYRIDINE)RUTHENIUM(II); CHEMILUMINESCENCE; TEMPERATURE; LINKING;
D O I
10.1002/anie.201304437
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chemomechanical reaction: The first octahedral ruthenium bipyridine complex that bears six polymerizable vinyl groups is used as an active cross-linker (see scheme, left). It is a key building block for cross-linked polymeric networks (right) thus allowing the construction of molecular architectures in chemomechanical soft materials. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:11494 / 11498
页数:5
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