Possible Superhardness of CrB4

被引：77

作者：

Knappschneider, Arno ^{[1
]}

Litterscheid, Christian ^{[1
]}

Dzivenko, Dmytro ^{[2
]}

Kurzman, Joshua A. ^{[3
,4
]}

Seshadri, Ram ^{[3
,4
]}

Wagner, Norbert ^{[5
]}

Beck, Johannes ^{[5
]}

Riedel, Ralf ^{[2
]}

Albert, Barbara ^{[1
]}

机构：

[1] Tech Univ Darmstadt, Eduard Zintl Inst Inorgan & Phys Chem, D-64287 Darmstadt, Germany

[2] Tech Univ Darmstadt, FB Mat & Geowissensch, D-64287 Darmstadt, Germany

[3] Univ Calif Santa Barbara, Dept Chem & Biochem, Dept Mat, Santa Barbara, CA 93106 USA

[4] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

[5] Univ Bonn, Inst Inorgan Chem, D-53121 Bonn, Germany

来源：

INORGANIC CHEMISTRY | 2013年 / 52卷 / 02期

基金：

美国国家科学基金会;

关键词：

CRYSTAL-STRUCTURE; BORIDE; MNB4;

D O I：

10.1021/ic3020404

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chromium tetraboride [orthorhombic, space group Pnnm (No. 58), a = 474.65(9) pm, b = 548.0(1) pm, c = 286.81(5) pm, and R value (all data) = 0.041], formerly described in space group Immm, was found not to be superhard, despite several theory-based prognoses. CrB4 shows an almost temperature-independent paramagnetism, consistent with low-spin Cr-I in a metallic compound. Conductivity measurements confirm the metallic character.

引用

页码：540 / 542

页数：3

共 50 条

[21] Lattice thermal conductivity of two-dimensional CrB4 and MoB4 monolayers against Slack's guideline
Liu, Xu
Jiang, Xi
Wang, Tong
Zhang, Zhen
Liu, Zhao
RESULTS IN PHYSICS, 2023, 51
[22] Fundamental constraints on the strength of transition-metal borides: The case of CrB4 (vol 87, 174106, 2013)
Li, Bing
Sun, Hong
Zang, Chenpeng
Chen, Changfeng
PHYSICAL REVIEW B, 2013, 88 (05):
[23] First-principle study on the structural, elastic and electronic properties of CrB4 hard material under different pressures
Li, Xiao-Hong
Zhang, Rui-Zhou
JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 694 : 733 - 738
[24] Open-framework beryllium phosphates with a zeolitic CrB4 topology and their structural analogues containing 12-ring channels
Wang, Kangcai
Li, Jing
Xu, Dingguo
Luo, Daibing
Lin, Zhien
CRYSTENGCOMM, 2015, 17 (10): : 2162 - 2167
[25] A novel two-dimensional whorled CrB4 and MoB4 as high-performance anode material for metal ion batteries
Masood, M. Kashif
Wang, Jing
Song, Juntao
Liu, Ying
APPLIED SURFACE SCIENCE, 2024, 652
[26] Crystal Structure Refinement and Bonding Patterns of CrB4: A Boron-Rich Boride with a Framework of Tetrahedrally Coordinated B Atoms
Knappschneider, Arno
Litterscheid, Christian
Kurzman, Joshua
Seshadri, Ram
Albert, Barbara
INORGANIC CHEMISTRY, 2011, 50 (21) : 10540 - 10542
[27] Interplay between p- and d- orbitals yields multiple Dirac states in one- and two-dimensional CrB4
Lopez-Bezanilla, Alejandro
2D MATERIALS, 2018, 5 (03):
[28] Generalized bond-strength model of Vickers hardness: Application to Cr4B, CrB, CrB2, CrB4, Mo2B, MoB2, OsB2, ReB2,WB2, WB3 and Ti1.87B50
Simunek, Antonin
Dusek, Michal
MECHANICS OF MATERIALS, 2017, 112 : 71 - 75
[29] POSSIBLE INDICATION OF MAGNETIC DEFORMATION IN BETA-CRB
STIFT, MJ
MONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, 1977, 178 (01) : 11 - 13
[30] Composition-Oxygen Partial Pressure Diagram of the Cr-B-O Ternary System Based on the Standard Gibbs Energies of Formation of CrB4, CrB2, Cr3B4, Cr5B3 and CrBO3 Determined by Solid Electrolyte
Yamamoto, Hiroaki
Taniguchi, Yoshitsugu
Nishiyama, Kazuto
Wada, Yoshitaka
Shibata, Kohei
Nozaki, Ai
Morishita, Masao
MATERIALS TRANSACTIONS, 2021, 62 (06) : 821 - 828

← 1 2 3 4 5 →