Silver(I) Complexes of Bisphosphines PhN{P(OC6H4C3H5-o)2}2 (1) and 2,6-{Ph2PC(O)}2C5H3N (2)

被引：1
|
作者：
Kashid, Vitthalrao S. [1 ]
Naik, Susmita [1 ]
Balakrishna, Maravanji S. [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Phosphorus Lab, Bombay 400076, Maharashtra, India
来源：
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES INDIA SECTION A-PHYSICAL SCIENCES | 2016年 / 86卷 / 04期
关键词：
Bisphosphine; Silver(I); Bidentate ligand; Coordination chemistry; GROUP-11; METAL-COMPLEXES; CATALYTIC INVESTIGATIONS; COORDINATION POLYMERS; DIPHOSPHINE LIGANDS; COPPER(I) COMPLEXES; DFT CALCULATIONS; PNP LIGAND; TETRANUCLEAR; PHENYLAMINOBIS(PHOSPHONITE); PHN(P(OC6H4OME-O)(2))(2);
D O I：
10.1007/s40010-016-0309-6
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Silver complexes of two bisphosphine ligands, PhN{P(OC6H4C3H5-o)(2)}(2) (1) and 2,6-{Ph2PC(O)}(2)C5H3N (2) have been described. Reactions of bisphosphines 1 and 2 with silver salts produce either mononuclear or dinuclear complexes (3-6) depending on the stoichiometry of the reagents and the reaction conditions. All new complexes have been characterized by spectroscopic and analytical data. The structure of spirocyclic complex, [Ag{2,6-{Ph2PC(O)}(2)C5H3N}(2)][CF3SO3] (6) has been confirmed by single crystal X-ray analysis.
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页码：601 / 604
页数：4
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