Synthesis and X-ray characterization of the quindecanuclear nickel/sulfur paramagnetic cluster [Ni15(μ3-S)6(μ4-S)9(PEt3)6]+

被引：7

作者：

Berti, E ^{[1
]}

Cecconi, F ^{[1
]}

Ghilardi, CA ^{[1
]}

Midollini, S ^{[1
]}

Orlandini, A ^{[1
]}

机构：

[1] CNR, Ist Studio Stereochim & Energet Composti Coordina, I-50132 Florence, Italy

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1999年 / 2卷 / 04期

关键词：

crystal structures; nickel complexes; sulfur complexes; paramagnetic complexes; cluster complexes;

D O I：

10.1016/S1387-7003(99)00033-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The quindecanuclear nickel/sulfur cluster [Ni-15(mu(3)-S)(6)(mu(4)-S)(9)(PEt3)(6)](+) has been isolated by reaction of Ni(ClO4)(2). 6H(2)O with H2S and PEt3 in ethanol/dichloromethane solution and has been characterized by X-ray diffraction studies. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：146 / 148

页数：3

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