Synthesis and X-ray characterization of the quindecanuclear nickel/sulfur paramagnetic cluster [Ni15(μ3-S)6(μ4-S)9(PEt3)6]+

被引：7
|
作者：
Berti, E [1 ]
Cecconi, F [1 ]
Ghilardi, CA [1 ]
Midollini, S [1 ]
Orlandini, A [1 ]
机构：
[1] CNR, Ist Studio Stereochim & Energet Composti Coordina, I-50132 Florence, Italy
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 1999年 / 2卷 / 04期
关键词：
crystal structures; nickel complexes; sulfur complexes; paramagnetic complexes; cluster complexes;
D O I：
10.1016/S1387-7003(99)00033-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The quindecanuclear nickel/sulfur cluster [Ni-15(mu(3)-S)(6)(mu(4)-S)(9)(PEt3)(6)](+) has been isolated by reaction of Ni(ClO4)(2). 6H(2)O with H2S and PEt3 in ethanol/dichloromethane solution and has been characterized by X-ray diffraction studies. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：146 / 148
页数：3
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