Intramolecular Diels-Alder reactions of carbon acetal-tethered trienes

被引:14
|
作者
Ainsworth, PJ
Craig, D
White, AJP
Williams, DJ
机构
[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND
[2] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,CHEM CRYSTALLOG LAB,LONDON SW7 2AY,ENGLAND
关键词
D O I
10.1016/0040-4020(96)00442-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The intramolecular Diels-Alder reactions of carbon acetal-tethered trienes 7, 10, 11 and 12 are described. The selectivities are rationalised in terms of the preferred ''inside-outside'' orientation of respectively the diene and dienophile tethering oxygen atoms. (C) 1996 Elsevier Science Ltd
引用
收藏
页码:8937 / 8946
页数:10
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