A novel open-framework zinc phosphite, Zn3(HPO3)4-Ni(en)2(H2O)2, templated by a transition-metal complex

被引：35
|
作者：
Lin, ZE [1 ]
Zhang, M [1 ]
Zheng, ST [1 ]
Yang, GY [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Coordinat & Hydrothermal Chem Grp, Fujian 350002, Peoples R China
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 05期
关键词：
open framework; inorganic solid; zinc; nickel; template synthesis;
D O I：
10.1002/ejic.200300601
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new three-dimensional zinc phosphite, Zn-3(HPO3)(4)- Ni(en)(2)(H2O)(2), which is the first example of an open-framework metal phosphite templated by a transition-metal complex, was hydrothermally synthesized. The connectivity of the strictly alternating ZnO4 and HPO3 units results in a three-dimensional framework with intersecting 8-ring and 12-ring channels, in which the transition-metal complexes reside. (C) Wiley-VCH Verlag GmbH Co.
引用
收藏
页码：953 / 955
页数：3
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