High Surface Area CeO2 Promoted Suzuki-Miyaura Cross-Coupling of Arylboronic Acids and Aryl Iodides

被引：6
|
作者：
Graziano Mayer, Marilyn [1 ]
Nador, Fabiana [1 ]
Alicia Volpe, Maria [2 ]
Radivoy, Gabriel [1 ]
机构：
[1] Univ Nacl Sur, Inst Quim Sur, INQUISUR CONICET UNS, Dept Quim, RA-8000 Bahia Blanca, Buenos Aires, Argentina
[2] PLAPIQUI CONICET UNS, RA-8000 Bahia Blanca, Buenos Aires, Argentina
来源：
SYNLETT | 2013年 / 24卷 / 03期
关键词：
biaryls; cross-coupling; cerium oxide; Suzuki-Miyaura reaction; palladium-free; PALLADIUM CATALYSTS; CARBON; CHLORIDES; EFFICIENT; WATER; CERIA; PD/C; LIGAND;
D O I：
10.1055/s-0032-1318111
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
High surface area cerium oxide (240 m(2)/g) efficiently promoted the Suzuki-Miyaura cross-coupling of aryl iodides with arylboronic acids, in the absence of palladium or any other transition-metal catalyst. Excellent selectivity towards the cross-coupling product was observed. Cerium oxide could be recovered and reused at least three times without any loss of activity.
引用
收藏
页码：338 / 342
页数：5
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