The promoting effect of alcohols in a new process of low-temperature synthesis of methanol from CO/CO2/H2

被引：21
|
作者：
Zeng, JQ
Tsubaki, N
Fujimoto, K
机构：
[1] Toyama Univ, Sch Engn, Dept Mat Syst & Life Sci, Toyama 9308555, Japan
[2] Chinese Acad Sci, Guangzhou Inst Chem, Guangzhou, Peoples R China
[3] Univ Kitakyushu, Sch Environm Engn, Kitakyushu, Fukuoka 8080135, Japan
来源：
FUEL | 2002年 / 81卷 / 01期
基金：
日本学术振兴会;
关键词：
methanol synthesis; alcohol; syngas; copper-zinc-oxide catalyst; formate;
D O I：
10.1016/S0016-2361(01)00123-5
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
The catalytic promoting effects of eleven different alcohols, as reaction medium, on the synthesis of methanol from feed gas of CO/CO2/H-2 on Cu/ZnO solid catalyst were investigated. Added alcohol altered the reaction route to realize a low-temperature synthesis method where formate was an intermediate. Many alcohols showed catalytic promoting effect for methanol formation at temperature as low as 443 K, remarkably lower than that in the present industrial 10 process. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：125 / 127
页数：3
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