Self-assembly of a 3-D self-catenated framework based on [V4O12]4- polyoxoanions and cobalt-organic polymer

被引：3

作者：

Qi, Yan-Fei ^{[1
]}

Xu, Kun ^{[1
]}

Lu, Li-Jun ^{[2
]}

Li, Juan ^{[1
]}

Wang, En-Bo ^{[3
]}

机构：

[1] Jilin Univ, Sch Publ Hlth, Changchun 130023, Peoples R China

[2] JiLin Entry Exit Inspect & Quarantine Bur, Changchun, Peoples R China

[3] NE Normal Univ, Dept Chem, Minist Educ, Key Lab Polyoxometalates Sci, Changchun 130024, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 66卷 / 07期

基金：

美国国家科学基金会; 中国博士后科学基金;

关键词：

Polyoxovanadates; Entangled networks; Organic-inorganic hybrid; Electrochemical property; METAL-OXIDE; POLYROTAXANE; CLUSTERS; NETWORK; 2D;

D O I：

10.1080/00958972.2013.777835

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of a flexible ligand with cobalt salt in the presence of polyoxovanadate produces a new composite solid, Co-2(btx)(4)V4O12, 1 (btx=1,4-bis(triazol-1-ylmethyl)benzene). The structure of 1 was determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis, IR spectrum, and TG analysis. Compound 1 exhibits a 3-D 4,6-connected self-catenated net constructed from [V4O12](4-) building blocks and the {Co(btx)(2)}(2+) 3-D metal-organic cation polymer. The electronic properties of 1 have been investigated.

引用

页码：1228 / 1237

页数：10

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