Self-assembly of a 3-D self-catenated framework based on [V4O12]4- polyoxoanions and cobalt-organic polymer

被引：3
|
作者：
Qi, Yan-Fei [1 ]
Xu, Kun [1 ]
Lu, Li-Jun [2 ]
Li, Juan [1 ]
Wang, En-Bo [3 ]
机构：
[1] Jilin Univ, Sch Publ Hlth, Changchun 130023, Peoples R China
[2] JiLin Entry Exit Inspect & Quarantine Bur, Changchun, Peoples R China
[3] NE Normal Univ, Dept Chem, Minist Educ, Key Lab Polyoxometalates Sci, Changchun 130024, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 66卷 / 07期
基金：
中国博士后科学基金; 美国国家科学基金会;
关键词：
Polyoxovanadates; Entangled networks; Organic-inorganic hybrid; Electrochemical property; METAL-OXIDE; POLYROTAXANE; CLUSTERS; NETWORK; 2D;
D O I：
10.1080/00958972.2013.777835
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of a flexible ligand with cobalt salt in the presence of polyoxovanadate produces a new composite solid, Co-2(btx)(4)V4O12, 1 (btx=1,4-bis(triazol-1-ylmethyl)benzene). The structure of 1 was determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis, IR spectrum, and TG analysis. Compound 1 exhibits a 3-D 4,6-connected self-catenated net constructed from [V4O12](4-) building blocks and the {Co(btx)(2)}(2+) 3-D metal-organic cation polymer. The electronic properties of 1 have been investigated.
引用
收藏
页码：1228 / 1237
页数：10
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