Palladium nanoparticles supported on Fe3O4/amino acid nanocomposite: Highly active magnetic catalyst for solvent-free aerobic oxidation of alcohols

被引：51
|
作者：
Zamani, Farzad [1 ,2 ]
Hosseini, Seyed Mohsen [1 ]
机构：
[1] Islamic Azad Univ, Shahreza Branch, Dept Chem, Shahreza 31186145, Isfahan, Iran
[2] Isfahan Univ Technol, Lab Appl Chem, Esfahan 8415683111, Iran
来源：
CATALYSIS COMMUNICATIONS | 2014年 / 43卷
关键词：
Heterogeneous magnetic catalyst; Palladium nanoparticle; Cysteine amino acid; Solvent-free aerobic oxidation of alcohol; High selectivity; BENZYL ALCOHOL; MESOPOROUS SILICA; SIZE CONTROL; EFFICIENT; FERRITE; PD;
D O I：
10.1016/j.catcom.2013.09.029
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this paper, Fe3O4 nanoparticles were coated by a number of amino acids, e.g. cysteine, serine, glycine and beta-alanine, via a simple method. Because of the surface modification of the magnetic nanoparticles with amino acid, the obtained magnetic nanocomposite is able to trap palladium nanoparticles through a strong interaction between the metal nanoparticles and the functional groups of amino acids. Among the synthesized nanocomposites, Fe3O4/cysteine-Pd exhibited the highest catalytic performance and excellent selectivity in the solvent-free aerobic oxidation of various alcohols, along with high level of reusability. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：164 / 168
页数：5
相关论文
共 50 条
  • [21] Fe3O4 Nanoparticles Anchored on Carbon Serve the Dual Role of Catalyst and Magnetically Recoverable Entity in the Aerobic Oxidation of Alcohols
    Geng, Longlong
    Zheng, Bin
    Wang, Xiang
    Zhang, Wenxiang
    Wu, Shujie
    Jia, Mingjun
    Yan, Wenfu
    Liu, Gang
    CHEMCATCHEM, 2016, 8 (04) : 805 - 811
  • [22] Palladium supported on poly (ionic liquid) entrapped magnetic nanoparticles as a highly efficient and reusable catalyst for the solvent-free Heck reaction
    Liu, Wendong
    Wang, Dongfang
    Duan, Yajing
    Zhang, Yahui
    Bian, Fengling
    TETRAHEDRON LETTERS, 2015, 56 (14) : 1784 - 1789
  • [23] Nanocomposite shuttle-supported palladium nanoparticles as a PH-triggered phase transfer catalyst for the aerobic oxidation of alcohols
    Zhu, Yaoqin
    Xu, Jian
    Lu, Ming
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2015, 12 (07) : 1213 - 1219
  • [24] Nanocomposite shuttle-supported palladium nanoparticles as a PH-triggered phase transfer catalyst for the aerobic oxidation of alcohols
    Yaoqin Zhu
    Jian Xu
    Ming Lu
    Journal of the Iranian Chemical Society, 2015, 12 : 1213 - 1219
  • [25] Nano Fe3O4 as magnetically recyclable catalyst for the synthesis of α-aminophosphonates in solvent-free conditions
    Reddy, B. V. Subba
    Krishna, A. Siva
    Ganesh, A. V.
    Kumar, G. G. K. S. Narayana
    TETRAHEDRON LETTERS, 2011, 52 (12) : 1359 - 1362
  • [26] Magnetic Nano Fe3O4 Catalyzed Solvent-Free Stereo- and Regioselective Aminolysis of Epoxides by Amines; a Green Method for the Synthesis of β-Amino Alcohols
    Kumar, Amit
    Parella, Ramarao
    Babu, Srinivasarao Arulananda
    SYNLETT, 2014, 25 (06) : 835 - 842
  • [27] Palladium-Supported Boron-Doped Hollow Carbon Spheres as Catalysts for the Solvent-free Aerobic Oxidation of Alcohols
    Ravat, Vilas
    Nongwe, Isaac
    Coville, Neil J.
    CHEMCATCHEM, 2012, 4 (12) : 1930 - 1934
  • [28] Fe3O4 Nanoparticles as Highly Efficient and Recyclable Catalyst for the Synthesis of 4-Hydroxy-3-[aryloyl(benzamido)methyl] coumarin under Solvent-Free Conditions
    Khodabakhshi, Saeed
    Abbasabadi, Masoud Khaleghi
    Heydarian, Samaneh
    Shirazi, Sanaz Gharehzadeh
    Marahel, Farzaneh
    LETTERS IN ORGANIC CHEMISTRY, 2015, 12 (07) : 465 - 470
  • [29] Palladium nanoparticles supported on organosilane-functionalized carbon nanotube for solvent-free aerobic oxidation of benzyl alcohol
    Yan, Yibo
    Chen, Yuanting
    Jia, Xinli
    Yang, Yanhui
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 156 : 385 - 397
  • [30] Green oxidation of alcohols by using hydrogen peroxide in water in the presence of magnetic Fe3O4 nanoparticles as recoverable catalyst
    Sadri, Fariba
    Ramazani, Ali
    Massoudi, Abdolhossain
    Khoobi, Mehdi
    Tarasi, Roghayeh
    Shafiee, Abbas
    Azizkhani, Vahid
    Dolatyari, Leila
    Joo, Sang Woo
    GREEN CHEMISTRY LETTERS AND REVIEWS, 2014, 7 (03) : 257 - 264
12345