Effects of Excess PbI2 Addition to CH3NH3PbI3-xClx Perovskite Solar Cells

被引:17
|
作者
Ueoka, Naoki [1 ]
Oku, Takeo [1 ]
Ohishi, Yuya [1 ]
Tanaka, Hiroki [1 ]
Suzuki, Atushi [1 ]
机构
[1] Univ Shiga Prefecture, Dept Mat Sci, Hikone, Shiga 5228533, Japan
基金
日本科学技术振兴机构;
关键词
Perovskite solar cells; PbI2; Fill factor; ORGANOMETAL HALIDE PEROVSKITES; PHOTOVOLTAIC DEVICES; PERFORMANCE; IODIDE; PASSIVATION; CHLORIDE; LAYERS;
D O I
10.1246/cl.171214
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
TiO2/CH3NH3PbI3-xClx-based photovoltaic cells with a small amount of excess added PbI2 were fabricated in ambient air. The fill factor and short-circuit current density were increased, which resulted in improvement of the photovoltaic performance. The recombination between a hole and an electron would be suppressed by the PbI2 formation, and the external quantum efficiencies were increased.
引用
收藏
页码:528 / 531
页数:4
相关论文
共 50 条
  • [11] Antiferroelectric Nature of CH3NH3PbI3-xClx Perovskite and Its Implication for Charge Separation in Perovskite Solar Cells
    Sewvandi, Galhenage A.
    Kodera, Kei
    Ma, Hao
    Nakanishi, Shunsuke
    Feng, Qi
    SCIENTIFIC REPORTS, 2016, 6
  • [12] The Role of Chlorine in the Formation Process of "CH3NH3PbI3-xClx" Perovskite
    Yu, Hui
    Wang, Feng
    Xie, Fangyan
    Li, Wenwu
    Chen, Jian
    Zhao, Ni
    ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (45) : 7102 - 7108
  • [13] Elucidating the charge carrier separation and working mechanism of CH3NH3PbI3-xClx perovskite solar cells
    Edri, Eran
    Kirmayer, Saar
    Mukhopadhyay, Sabyasachi
    Gartsman, Konstantin
    Hodes, Gary
    Cahen, David
    NATURE COMMUNICATIONS, 2014, 5
  • [14] Degradation of inverted architecture CH3NH3PbI3-xClx perovskite solar cells due to trapped moisture
    Bracher, Christopher
    Freestone, Benjamin G.
    Mohamad, David K.
    Smith, Joel A.
    Lidzey, David G.
    ENERGY SCIENCE & ENGINEERING, 2018, 6 (01) : 35 - 46
  • [15] Effects of hot airflow during spin-coating process on CH3NH3PbI3-xClx perovskite solar cells
    Tanaka, Hiroki
    Ohishi, Yuya
    Oku, Takeo
    IRAGO CONFERENCE 2017: A 360-DEGREE OUTLOOK ON CRITICAL SCIENTIFIC AND TECHNOLOGICAL CHALLENGES FOR A SUSTAINABLE SOCIETY, 2018, 1929
  • [16] Effect of PbI2 surface treatment with DMSO vapor on the properties and photodetector characteristics of CH3NH3PbI3-xClx perovskite films synthesized by a PbS-to-PbI2-to-perovskite sequence
    Cota-Leal, M.
    Paredes-Sotelo, E.
    Sotelo-Lerma, M.
    Garcia-Valenzuela, J. A.
    ORGANIC ELECTRONICS, 2020, 84
  • [17] Performance and Stability Comparison of Low-Cost Mixed Halide Perovskite Solar Cells: CH3NH3PbI3-xClx and CH3NH3PbI3-xSCNx
    Poespawati, Nji Raden
    Sulistianto, Junivan
    Abuzairi, Tomy
    Purnamaningsih, Retno Wigajatri
    INTERNATIONAL JOURNAL OF PHOTOENERGY, 2020, 2020
  • [18] Efficiencies of perovskite hybrid solar cells influenced by film thickness and morphology of CH3NH3PbI3-xClx layer
    Wang, Kai
    Liu, Chang
    Du, Pengcheng
    Chen, Long
    Zhu, Jiahua
    Karim, Alamgir
    Gong, Xiong
    ORGANIC ELECTRONICS, 2015, 21 : 19 - 26
  • [19] Annealing Induced Re-crystallization in CH3NH3PbI3-xClx for High Performance Perovskite Solar Cells
    Yang, Yingguo
    Feng, Shanglei
    Li, Meng
    Xu, Weidong
    Yin, Guangzhi
    Wang, Zhaokui
    Sun, Baoquan
    Gao, Xingyu
    SCIENTIFIC REPORTS, 2017, 7
  • [20] Surfactant enhanced surface coverage of CH3NH3PbI3-xClx perovskite for highly efficient mesoscopic solar cells
    Ding, Yanli
    Yao, Xin
    Zhang, Xiaodan
    Wei, Changchun
    Zhao, Ying
    JOURNAL OF POWER SOURCES, 2014, 272 : 351 - 355