Solution growth and morphology of CH3NH3PbBr3 single crystals in different solvents

被引：17

作者：

Su, Jing ^{[1
]}

Sang, Lin ^{[1
]}

Wang, Di ^{[2
,3
,4
]}

Lu, Di ^{[1
]}

Wang, Wanfu ^{[1
]}

Wen, Yan ^{[1
]}

机构：

[1] Nanjing Univ Informat Sci & Technol, Sch Phys & Optoelect Engn, Nanjing 210044, Jiangsu, Peoples R China

[2] Nanjing Univ, Natl Lab Solid State Microstruct, Nanjing 210093, Jiangsu, Peoples R China

[3] Nanjing Univ, Dept Phys, Nanjing 210093, Jiangsu, Peoples R China

[4] Nanjing Univ, Collaborat Innovat Ctr Adv Microstruct, Nanjing 210093, Jiangsu, Peoples R China

来源：

CRYSTAL RESEARCH AND TECHNOLOGY | 2016年 / 51卷 / 11期

基金：

中国国家自然科学基金;

关键词：

CH3NH3PbBr3; solution crystal growth; solubility; morphology; solar cell; ORGANOMETAL HALIDE PEROVSKITES; SENSITIZED SOLAR-CELLS; LEAD HALIDES; I CRYSTALS; DIFFUSION; BR; DEPOSITION;

D O I：

10.1002/crat.201600193

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In this work, large-sized CH3NH3PbBr3 single crystals were successful grown using solution evaporation method with hydrohalic acid and N, N-Dimethylformamide (DMF) as solvent respectively. The lattice parameters of cubic CH3NH3PbBr3 were estimated using XRD method. The solubility of CH3NH3PbBr3 in hydrobromic acid was determined at the temperature range between 20 degrees C-90 degrees C. A special micro-solution crystallizer was designed to in-situ study the morphology of CH3NH3PbBr3 crystal. The largest crystal face was indexed by the XRD patterns and it would be {110} for CH3NH3PbBr3 grown from HBr solution and {100} from DMF solution. The results show that solvent would affect the morphology and crystal habit greatly during crystal growth from solution.

引用

页码：650 / 655

页数：6

共 50 条

[31] Low surface recombination velocity in solution-grown CH3NH3PbBr3 perovskite single crystal
Yang, Ye
Yan, Yong
Yang, Mengjin
Choi, Sukgeun
Zhu, Kai
Luther, Joseph M.
Beard, Matthew C.
NATURE COMMUNICATIONS, 2015, 6
[32] Structure Evolution of CH3NH3PbBr3 Single Crystal Grown in N,N-Dimethylformamide Solution
Chen, Feng
Xu, Chunxiang
Xu, Qingyu
Zhu, Yizhi
Zhu, Zhu
Liu, Wei
Dong, Xiuxiu
Qin, Feifei
Shi, Zengliang
CRYSTAL GROWTH & DESIGN, 2018, 18 (05) : 3132 - 3137
[33] Metal contact and carrier transport in single crystalline CH3NH3PbBr3 perovskite
Lin, Chun-Ho
Li, Ting-You
Cheng, Bin
Liu, Changxu
Yang, Chih-Wen
Ke, Jr-Jian
Wei, Tzu-Chiao
Li, Lain-Jong
Fratalocchi, Andrea
He, Jr-Hau
NANO ENERGY, 2018, 53 : 817 - 827
[34] Low surface recombination velocity in solution-grown CH3NH3PbBr3 perovskite single crystal
Ye Yang
Yong Yan
Mengjin Yang
Sukgeun Choi
Kai Zhu
Joseph M. Luther
Matthew C. Beard
Nature Communications, 6
[35] Nontemplate Synthesis of CH3NH3PbBr3 Perovskite Nanoparticles
Schmidt, Luciana C.
Pertegas, Antonio
Gonzalez-Carrero, Soranyel
Malinkiewicz, Olga
Agouram, Said
Minguez Espallargas, Guillermo
Bolink, Henk J.
Galian, Raquel E.
Perez-Prieto, Julia
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (03) : 850 - 853
[36] Nontemplate synthesis of CH3NH3PbBr3 perovskite nanoparticles
Galian, R.E. (raquel.galian@uv.es), 1600, American Chemical Society (136):
[37] The anti-polar structure of CH3NH3PbBr3
Mashiyama, H.
Kawamura, Y.
Kubota, Y.
JOURNAL OF THE KOREAN PHYSICAL SOCIETY, 2007, 51 (02) : 850 - 853
[38] Exciton-exciton scattering in perovskite CH3NH3PbBr3 single crystal
Kunugita, Hideyuki
Kiyota, Yuki
Udagawa, Yosuke
Takeoka, Yuko
Nakamura, Yuiga
Sano, Junro
Matsushita, Tomonori
Kondo, Takashi
Ema, Kazuhiro
JAPANESE JOURNAL OF APPLIED PHYSICS, 2016, 55 (06)
[39] Electronic Structure and Optical Properties of α-CH3NH3PbBr3 Perovskite Single Crystal
Park, Ji-Sang
Choi, Sukgeun
Yan, Yong
Yang, Ye
Luther, Joseph M.
Wei, Su-Huai
Parilla, Philip
Zhu, Kai
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2015, 6 (21): : 4304 - 4308
[40] Interpretation of the giant dielectric constant in the single crystal of the CH3NH3PbBr3 perovskite
Ben Bechir, Mohamed
Almeshal, Abdelkareem
Dhaou, Mohamed Houcine
MATERIALS RESEARCH BULLETIN, 2022, 149

← 1 2 3 4 5 →