The Last Globally Stable Extended Alkane

被引：95

作者：

Luettschwager, Nils O. B. ^{[1
]}

Wassermann, Tobias N. ^{[1
]}

Mata, Ricardo A. ^{[1
]}

Suhm, Martin A. ^{[1
]}

机构：

[1] Univ Gottingen, Inst Phys Chem, D-37077 Gottingen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 01期

关键词：

chain molecules; conformational analysis; dispersion; molecular folding; Raman spectroscopy; ENTHALPY DIFFERENCE; BASIS-SETS; MOLECULES;

D O I：

10.1002/anie.201202894

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mother of all folding: Cold isolated linear alkanes CnH 2n+2 prefer an extended alltrans conformation before cohesive forces between the chain ends induce a folded hairpin structure for longer chains. It is shown by Raman spectroscopy at 100-150 K that the folded structure becomes more stable beyond nC=17 or 18 carbon atoms. High-level quantum-chemical calculations yield nC=17±1 as the critical chain length. © 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：463 / 466

页数：4

共 50 条

[41] GLOBALLY STABLE AND EXPONENTIALLY CONVERGENT ADAPTIVE-CONTROL
JANECKI, D
INTERNATIONAL JOURNAL OF CONTROL, 1986, 43 (02) : 601 - 613
[42] Globally asymptotically stable formation control of three agents
Wang, Qin
Tian, Yu-Ping
Xu, Yaojin
JOURNAL OF SYSTEMS SCIENCE & COMPLEXITY, 2012, 25 (06) : 1068 - 1079
[43] Globally asymptotically stable tracking control of mobile robots
Kim, DH
Oh, JH
PROCEEDINGS OF THE 1998 IEEE INTERNATIONAL CONFERENCE ON CONTROL APPLICATIONS, VOLS 1 AND 2, 1996, : 1297 - 1301
[44] Globally asymptotically stable tracking control for a trailer system
Kim, DH
Oh, JH
JOURNAL OF ROBOTIC SYSTEMS, 2002, 19 (05): : 199 - 205
[45] Design of globally stable controllers for a class of chaotic systems
Apostolou, N
King, RE
INTERNATIONAL JOURNAL OF SYSTEMS SCIENCE, 2002, 33 (05) : 379 - 386
[46] A Globally Stable Adaptive Controller for the Human Shank Dynamics
Ortega, R.
Bobstov, A.
de Queiroz, M.
Yang, R.
Nikolaev, N.
JOURNAL OF DYNAMIC SYSTEMS MEASUREMENT AND CONTROL-TRANSACTIONS OF THE ASME, 2023, 145 (08):
[47] Natural Casing Trade Globally stable at a high Level
不详
FLEISCHWIRTSCHAFT, 2017, 97 (10): : 63 - 63
[48] Globally Asymptotically Stable Equilibrium Points in Kukles Systems
Fabio Scalco Dias
Luis Fernando Mello
Qualitative Theory of Dynamical Systems, 2020, 19
[49] Globally stable minimal mass compressive tensegrity structures
Skelton, Robert E.
Montuori, Rosario
Pecoraro, Vincenza
COMPOSITE STRUCTURES, 2016, 141 : 346 - 354
[50] The globally stable solution of a stochastic nonlinear Schrodinger equation
Khasin, M.
Kosloff, R.
JOURNAL OF PHYSICS A-MATHEMATICAL AND THEORETICAL, 2008, 41 (36)

← 1 2 3 4 5 →