Gas-phase calorimetry of protonated water clusters

被引:24
|
作者
Schmidt, M. [1 ]
von Issendorff, B. [2 ]
机构
[1] Univ Paris 11, CNRS, Aime Cotton Lab, Bat 505, F-91405 Orsay, France
[2] Univ Freiburg, Fak Phys, D-79104 Freiburg, Germany
来源
JOURNAL OF CHEMICAL PHYSICS | 2012年 / 136卷 / 16期
关键词
FLIGHT MASS SPECTROMETERS; COLLISIONAL ACTIVATION; GLASS-TRANSITION; HEAT-CAPACITY; SOLID WATER; ION; ICE; TEMPERATURES; CONFINEMENT; EVAPORATION;
D O I
10.1063/1.4705266
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Protonated water clusters with 60 to 79 molecules have been studied by nanocalorimetry. The technique is based on multi-collision excitations of the accelerated clusters with helium. The caloric curves indicate transitions that resemble those of water clusters charged by an excess electron, but the transition temperatures of the protonated clusters are higher. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4705266]
引用
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页数:9
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