Spray drying thermoplastic starch formulations: Need for processing aids and plasticizers?

被引：16
|
作者：
Niazi, Muhammad Bilal Khan [1 ]
Zijlstra, Mark [1 ,2 ]
Broekhuis, Antonius A. [1 ]
机构：
[1] Univ Groningen, Inst Technol & Management, Dept Chem Engn, NL-9747 AG Groningen, Netherlands
[2] Champ Technol Europe BV, NL-7491 AE Delden, Netherlands
来源：
EUROPEAN POLYMER JOURNAL | 2013年 / 49卷 / 07期
关键词：
Amorphous; Retrogradation; Molecular weight; Plasticizer; Spray drying; Thermoplastic starch; POTATO STARCH; PHYSICOCHEMICAL PROPERTIES; MECHANICAL-PROPERTIES; GLASS-TRANSITION; MOLECULAR-WEIGHT; THERMAL-BEHAVIOR; AMIDE GROUPS; CRYSTALLINITY; TEMPERATURE; POLYOLS;
D O I：
10.1016/j.eurpolymj.2013.04.016
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Retrogradation of amorphous thermoplastic starch (TPS) films obtained by compression moulding of spray dried amorphous powder was investigated. The aim of the work was to study the influence of malto-oligosaccharide molecular weight, i.e. dextrose equivalents (DEs), on the performance of the powders and the films. Amorphous TPS films were obtained, irrespective of the additive used. At a relative humidity (RH) of 0% and 50% all samples maintained their amorphous nature while at RH100% retrogradation was suppressed for all formulated starch films. It is shown that the rate of moisture uptake, and as a consequence, the rate of retrogradation, depends on the molecular weight of the additive. FT-IR and TGA measurements proved a more effective interaction of starch with low molecular weight additives such as maltose and glucose syrup (DE 38.2) than for the higher molecular weight maltodextrine (DE 19.1). (c) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1861 / 1870
页数：10
相关论文
共 50 条
  • [41] Analysis of the Results of Research on Spray Drying of Starch Suspension
    Tolmac, Dragisa
    Prvulovic, Slavica
    Tolmac, Jasna
    Stankov, Sanja
    FME TRANSACTIONS, 2018, 46 (01): : 129 - 132
  • [42] Production of amorphous starch powders by solution spray drying
    Niazi, Muhammad B. K.
    Broekhuis, Antonius A.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2012, 126 : E143 - E153
  • [43] Dynamic Mechanical Spectroscopy with Cylindrical Geometry: Application to the Comparison of Various Plasticizers of Thermoplastic Starch
    Basson, Jonathan
    Carrot, Christian
    Chalamet, Yvan
    Mignard, Nathalie
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2024, 225 (21)
  • [44] Injection-molded thermoplastic cassava starch modified with single and mixed polyol plasticizers
    Khanoonkon, Nattaporn
    Dang, Khanh Minh
    Yoksan, Rangrong
    INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2024, 280
  • [45] Effect of cardanol-based plasticizers on thermoplastic cassava (Manihot esculenta) starch properties
    Adjoumane, Marcellin M. A.
    Edja, Assanvo F.
    Doe-Mensah, Jackson
    Boa, David
    Driscoll, Mark
    INDUSTRIAL CROPS AND PRODUCTS, 2023, 203
  • [46] Influence of Choline Chloride/Urea and Glycerol Plasticizers on the Mechanical Properties of Thermoplastic Starch Plastics
    Staker, Jacob
    Schott, Sydney
    Singh, Riya
    Collier, Kourtney
    Druschel, Gregory
    Siegel, Amanda P.
    Tovar, Andres
    POLYMERS, 2024, 16 (06)
  • [47] OXIDIZED POTATO STARCH BASED THERMOPLASTIC FILMS: EFFECT OF COMBINATION OF POLAR AND AMPHIPHILIC PLASTICIZERS
    Niazi, Muhammad B. K.
    Broekhuis, Antonius A.
    PROCEEDINGS OF THE 8TH INTERNATIONAL CONFERENCE ON POLYSACCHARIDES-GLYCOSCIENCE, 2012, : 111 - 114
  • [48] Oxidized potato starch based thermoplastic films: Effect of combination of hydrophilic and amphiphilic plasticizers
    Niazi, Muhammad Bilal Khan
    Broekhuis, Antonius A.
    STARCH-STARKE, 2016, 68 (7-8): : 785 - 795
  • [49] Spray Drying Processing: granules production and drying kinetics of droplets
    Mondragon, Rosa
    Enrique Julia, J.
    Barba, Antonio
    Carlos Jarque, Juan
    BOLETIN DE LA SOCIEDAD ESPANOLA DE CERAMICA Y VIDRIO, 2013, 52 (04): : 159 - 168
  • [50] Improved viability of spray dried brewer's yeast by using starch (grits) and maltodextrin as processing aids
    Luna-Solano, G
    Salgado-Cervantes, MA
    Garcia-Alvarado, MA
    Rodriguez-Jimenes, G
    JOURNAL OF FOOD PROCESS ENGINEERING, 2000, 23 (06) : 453 - 462
12345