Enantioselective cathodic reduction of some prochiral ketones in the presence of (1R,2S)(-)-N,N-dimethylephedrinium tetrafluoroborate at a mercury pool cathode

被引：16

作者：

Yadav, AK ^{[1
]}

Singh, A ^{[1
]}

机构：

[1] Univ Rajasthan, Dept Chem, Jaipur 302004, Rajasthan, India

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2002年 / 75卷 / 03期

关键词：

D O I：

10.1246/bcsj.75.587

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The enantioselective cathodic reduction of some prochiral ketones viz. acetophenone (I), propiophenone (11), butyrophenone (III), valerophenone (IV), isobutyrophenone (V), and pivalophenone (VI) has been accomplished at a mercury pool cathode in N,N-dimethylformamide (DMF)-water (90: 10) using tetrabutylammonium fluoroborate (TBA.BF4) as a supporting electrolyte in the presence of (1R,2S)-(-)N,N-dimethylephedrinium tetrafluoroborate (DET). Cyclic voltammetric investigations have been carried out and a probable mechanism of the process has been presented.

引用

页码：587 / 588

页数：2

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