Enantioselective cathodic reduction of some prochiral ketones in the presence of (1R,2S)(-)-N,N-dimethylephedrinium tetrafluoroborate at a mercury pool cathode

被引：16
|
作者：
Yadav, AK [1 ]
Singh, A [1 ]
机构：
[1] Univ Rajasthan, Dept Chem, Jaipur 302004, Rajasthan, India
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2002年 / 75卷 / 03期
关键词：
D O I：
10.1246/bcsj.75.587
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The enantioselective cathodic reduction of some prochiral ketones viz. acetophenone (I), propiophenone (11), butyrophenone (III), valerophenone (IV), isobutyrophenone (V), and pivalophenone (VI) has been accomplished at a mercury pool cathode in N,N-dimethylformamide (DMF)-water (90: 10) using tetrabutylammonium fluoroborate (TBA.BF4) as a supporting electrolyte in the presence of (1R,2S)-(-)N,N-dimethylephedrinium tetrafluoroborate (DET). Cyclic voltammetric investigations have been carried out and a probable mechanism of the process has been presented.
引用
收藏
页码：587 / 588
页数：2
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