New polymer synthesis by nitroxide mediated living radical polymerizations

被引：3509

作者：

Hawker, CJ ^{[1
]}

Bosman, AW ^{[1
]}

Harth, E ^{[1
]}

机构：

[1] IBM Corp, Almaden Res Ctr, San Jose, CA 95120 USA

来源：

CHEMICAL REVIEWS | 2001年 / 101卷 / 12期

关键词：

D O I：

10.1021/cr990119u

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polymer synthesis by nitroxide living radical polymerization was discussed. The advantage of this method is its ability to accommodate functional groups and diverse families of monomers and copolymers and its stability of the initiating species. Results showed that a variety of chemical transformations can be performed with no deleterious effect on the initiating ability of the alkoxyamine initiator.

引用

页码：3661 / 3688

页数：28

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