New polymer synthesis by nitroxide mediated living radical polymerizations

被引:3509
|
作者
Hawker, CJ [1 ]
Bosman, AW [1 ]
Harth, E [1 ]
机构
[1] IBM Corp, Almaden Res Ctr, San Jose, CA 95120 USA
关键词
D O I
10.1021/cr990119u
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Polymer synthesis by nitroxide living radical polymerization was discussed. The advantage of this method is its ability to accommodate functional groups and diverse families of monomers and copolymers and its stability of the initiating species. Results showed that a variety of chemical transformations can be performed with no deleterious effect on the initiating ability of the alkoxyamine initiator.
引用
收藏
页码:3661 / 3688
页数:28
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