Unraveling Sunlight by Transparent Organic Semiconductors toward Photovoltaic and Photosynthesis

被引:145
|
作者
Liu, Yugiang [1 ,2 ]
Cheng, Pei [1 ]
Li, Tengfei [4 ]
Wang, Rui [1 ]
Li, Yaowen [3 ]
Chang, Sheng-Yung [1 ]
Zhu, Yuan [1 ]
Cheng, Hao-Wen [1 ,5 ]
Wei, Kung-Hwa [5 ]
Zhan, Xiaowei [4 ]
Sun, Baoquan [2 ]
Yang, Yang [1 ]
机构
[1] Univ Calif Los Angeles, Dept Mat Sci & Engn, Los Angeles, CA 90095 USA
[2] Soochow Univ, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Inst Funct Nano & Soft Mat FUNSOM, Joint Int Res Lab Carbon Based Funct Mat & Device, Suzhou 215123, Peoples R China
[3] Soochow Univ, Lab Adv Optoelect Mat, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China
[4] Peking Univ, Dept Mat Sci & Engn, Coll Engn, Key Lab Polymer Chem & Phys,Minist Educ, Beijing 100871, Peoples R China
[5] Natl Chiao Tung Univ, Dept Mat Sci & Engn, Ctr Emergent Funct Matter Sci, Hsinchu 30050, Taiwan
基金
中国国家自然科学基金;
关键词
infrared light; transparent; flexible; organic photovoltaic; photosynthesis; POLYMER SOLAR-CELLS; HIGH-EFFICIENCY; ACCEPTOR; DESIGN;
D O I
10.1021/acsnano.8b08577
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Because the visible and the infrared (IR) regions take up similar to 47% and similar to 51% of the energy in the solar spectrum (AM 1.5G standard), respectively, utilizing the visible light for plant growth and the IR light for power generation is potentially extremely exciting. IR-absorbing organic semiconductors, with localized IR absorption and visible-light transmittance, would be promising materials for this purpose. Here, flexible transparent organic photovoltaics (TOPVs) based on IR-absorbing organic materials were proposed, which can be a simple, low-cost, and promising way to utilize the IR light for electricity generation, and the penetrated visible light will be utilized for photosynthesis in plants. A power-conversion efficiency of similar to 10% with an average visible transmittance of 34% was achieved for TOPV devices. Meanwhile, the side-by-side comparison showed that plants grown under the TOPVs filtered light, and those under normal sunlight yielded very similar results. These outcomes demonstrated the results from TOPV devices beyond simple photovoltaic applications.
引用
收藏
页码:1071 / 1077
页数:7
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