Synthesis and structures of the triple-decker type complexes CpCo(μ-1,3-C3B2Me5)MX2L (M=Rh and Ir; X=Cl and Br; L=Me2SO and PPh3)

被引：0

作者：

Romanov, Alexander S. ^{[1
,2
]}

Muratov, Dmitry V. ^{[1
]}

Antipin, Mikhail Yu ^{[1
,2
]}

Siebert, Walter ^{[3
]}

Kudinov, Alexander R. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Organoelement Cpds, Moscow 119991, Russia

[2] New Mexico Highlands Univ, Dept Nat Sci, Las Vegas, NM 87701 USA

[3] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2012年 / 715卷

关键词：

Boron; Cobalt; Heterocycles; Rhodium; Iridium; Triple-decker complexes; RHODIUM; LIGANDS; HYDROGENATION;

D O I：

10.1016/j.jorganchem.2012.06.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dimeric triple-decker type halides [CpCo(mu-1,3-C3B2Me5)MX2](2) (M = Rh, X = Cl, 1; M = Ir, X = Cl, 2; M = Rh, X = Br, 3; M = Ir, X = Br, 4) react with Me2SO and PPh3 giving adducts CpCo(mu-1,3-C3B2Me5) M(L) X-2 (5-12). The Me2SO ligand is S-bonded to the metal atom in the solid state, while in acetone it is O-bonded. Structures of 5-12 were confirmed by X-ray diffraction. (C) 2012 Elsevier B. V. All rights reserved.

引用

页码：136 / 140

页数：5

共 50 条

[31] COMPLEXES OF THE PLATINUM METALS .23. SYNTHESIS OF THE NITROSYL CARBOXYLATE COMPLEXES [M(O2CR)2(NO)(PPH3)2] (M = RH OR IR - R = CF3, C2F5, OR C6F5) - CRYSTAL AND MOLECULAR-STRUCTURES OF THE TRIFLUOROACETATE DERIVATIVES [M(O2CCF3)2(NO)(PPH3)2]
DOBSON, A
MOORE, DS
ROBINSON, SD
GALAS, AMR
HURSTHOUSE, MB
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (04): : 611 - 616
[32] PENTAKIS(METHOXYCARBONYL)CYCLOPENTADIENE CHEMISTRY .12. SOME RHODIUM AND IRIDIUM DERIVATIVES - X-RAY CRYSTAL-STRUCTURES OF RH(ETA-4-C8H12)(ETA-5-C5(CO2ME)5), RH(AZB)2(C5(CO2ME)5), AND [M(CO)(OC(OH)ME)(PPH3)2] [C5(CO2ME)5] (M = RH AND IR)
BRUCE, MI
HUMPHREY, PA
SKELTON, BW
WHITE, AH
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 361 (03) : 369 - 390
[33] CHEMISTRY AND CATALYTIC PROPERTIES OF RUTHENIUM AND OSMIUM COMPLEXES .2. SYNTHESIS AND CHARACTERIZATION OF NEW MONONUCLEAR AND DINUCLEAR COMPLEXES WITH HYDRIDE, CARBOXYLATE, AND PHOSPHINE-LIGANDS - X-RAY CRYSTAL AND MOLECULAR-STRUCTURES OF OSBR(OCOME)(CO)(PPH3)2, RUCL(OCOME)(CO)(PPH3)2, AND [PPH3ME]+[RU2CL2(MU-CL)3(CO)2(PPH3)2]-,
SANCHEZDELGADO, RA
THEWALT, U
VALENCIA, N
ANDRIOLLO, A
MARQUEZSILVA, RL
PUGA, J
SCHOLLHORN, H
KLEIN, HP
FONTAL, B
INORGANIC CHEMISTRY, 1986, 25 (08) : 1097 - 1106
[34] Synthesis of double incomplete-cubane clusters [PPh4]2[(η5-C5Me5)MS3Cu3X3]2 (M = Mo, W; X = Cl, Br) and reactions with PPh3, dppm (1,2-bis(diphenylphosphino)methane), and AsPh3
Lang, JP
Kawaguchi, H
Ohnishi, S
Tatsumi, K
INORGANICA CHIMICA ACTA, 1998, 283 (01) : 136 - 144
[35] NUCLEOPHILIC DISCRIMINATION AND THE TRANS EFFECT - THE KINETICS OF DISPLACEMENT OF X FROM TRANS-[PT(L)(X)CL2]N- (L=ME2SO, ET2S, PME3, PET3, PPH3, OR ASET3, X=CL, N=1, X=MEOH, N=O) BY NEUTRAL AND ANIONIC NUCLEOPHILES
TOBE, ML
TREADGOLD, AT
CATTALINI, L
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (09): : 2347 - 2352
[36] Reaction of CpRu(PPh3)2Cl with six-member cyclothioethers.: Structures of the [CpRu(PPh3)xL]Y complexes (L = pentamethylene sulfide, x=2, Y=BF4-; L = 1,3-dithiane; 1,3,5-trithiane, x=2, Y=CF3SO3-; L=1,4-dithiane, x=1, Y=BF4-)
Green, M
Draganjac, M
Jiang, YJ
Nave, PM
Cordes, AW
Bryan, CD
Dixon, JK
Folkert, SL
Yu, CH
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2003, 33 (5-6) : 473 - 479
[37] Reaction of CpRu(PPh3)2Cl with six-member cyclothioethers. Structures of the [CpRu(PPh3)xL]Y complexes (L = pentamethylene sulfide, x = 2, Y = BF4−; L = 1,3-dithiane; 1,3,5-trithiane, x = 2, Y = CF3SO3−; L = 1,4-dithiane, x = 1, Y = BF4−)
Mark Green
M. Draganjac
Yanjing Jiang
Paul M. Nave
A.W. Cordes
C.D. Bryan
J.K. Dixon
S.L. Folkert
C.-H. Yu
Journal of Chemical Crystallography, 2003, 33 : 473 - 479
[38] REACTIVITY OF BRIDGED DINUCLEAR TRANSITION-METAL COMPLEXES OF THE TYPE ME2SI[C5H4FE(CO)(L)I]2,L=PPH3 AND P(OPH)3 - SYNTHESIS AND CHARACTERIZATION OF THE MIXED IODO-ALKYL COMPLEX ME2SI[C5H4FE(CO)(PPH3)(ETA-1-BUTYL)]-[C5H4FE(CO)-(PPH3)I]
NELSON, GO
WRIGHT, ME
ORGANOMETALLICS, 1982, 1 (03) : 565 - 568
[39] SYNTHESIS AND CHARACTERIZATION OF HG(II) COMPLEXES OF ME3MCH2SEME, (M = SI, GE) - CRYSTAL-STRUCTURES OF [HGX2(ME3SICH2SEME)]2, X = CL, BR, I
CHADHA, RK
DRAKE, JE
MCMANUS, NT
MISLANKAR, A
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1987, 65 (09): : 2305 - 2311
[40] PHOTOFRAGMENTATION VOLTAMMETRY STUDIES OF THE AMINOCARBENE COMPLEXES [(ETA(5)-C5H5)FE(CO)(L)(=C(NHR(1))(R(2))]BF4 [L = PPH3, P(P-TOL)3, R(1) = ME, CH2PH, R(2) = ME, BU]
DAVIES, SG
METZLER, MR
WATKINS, WC
COMPTON, RG
BOOTH, J
EKLUND, JC
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1993, (09): : 1603 - 1609

← 1 2 3 4 5 →