Synthesis and structures of the triple-decker type complexes CpCo(μ-1,3-C3B2Me5)MX2L (M=Rh and Ir; X=Cl and Br; L=Me2SO and PPh3)

被引：0
|
作者：
Romanov, Alexander S. [1 ,2 ]
Muratov, Dmitry V. [1 ]
Antipin, Mikhail Yu [1 ,2 ]
Siebert, Walter [3 ]
Kudinov, Alexander R. [1 ]
机构：
[1] Russian Acad Sci, Inst Organoelement Cpds, Moscow 119991, Russia
[2] New Mexico Highlands Univ, Dept Nat Sci, Las Vegas, NM 87701 USA
[3] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2012年 / 715卷
关键词：
Boron; Cobalt; Heterocycles; Rhodium; Iridium; Triple-decker complexes; RHODIUM; LIGANDS; HYDROGENATION;
D O I：
10.1016/j.jorganchem.2012.06.003
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The dimeric triple-decker type halides [CpCo(mu-1,3-C3B2Me5)MX2](2) (M = Rh, X = Cl, 1; M = Ir, X = Cl, 2; M = Rh, X = Br, 3; M = Ir, X = Br, 4) react with Me2SO and PPh3 giving adducts CpCo(mu-1,3-C3B2Me5) M(L) X-2 (5-12). The Me2SO ligand is S-bonded to the metal atom in the solid state, while in acetone it is O-bonded. Structures of 5-12 were confirmed by X-ray diffraction. (C) 2012 Elsevier B. V. All rights reserved.
引用
收藏
页码：136 / 140
页数：5
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