Highly efficient transformation of levulinic acid into pyrrolidinones by iridium catalysed transfer hydrogenation

被引：112

作者：

Wei, Yawen ^{[1
]}

Wang, Chao ^{[1
]}

Jiang, Xue ^{[1
]}

Xue, Dong ^{[1
]}

Li, Jia ^{[1
]}

Xiao, Jianliang ^{[1
,2
]}

机构：

[1] Shaanxi Normal Univ, Dept Chem & Chem Engn, Minist Educ, Key Lab Appl Surface & Colloid Chem, Xian 710062, Peoples R China

[2] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 47期

基金：

美国国家科学基金会;

关键词：

ASYMMETRIC TRANSFER HYDROGENATION; GAMMA-VALEROLACTONE; REDUCTIVE AMINATION; SELECTIVE HYDROGENATION; FORMIC-ACID; BIOMASS; CONVERSION; FUELS; KETONES; COMPLEXES;

D O I：

10.1039/c3cc41661e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Levulinic acid (LA) is transformed into pyrrolidinones via iridium-catalysed reductive amination using formic acid as the hydrogen source under aqueous conditions. The catalytic system is the most active and performs under the mildest conditions ever reported for the reductive amination of LA.

引用

页码：5408 / 5410

页数：3

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