Highly efficient hydrogenation of biomass-derived levulinic acid to γ-valerolactone catalyzed by iridium pincer complexes

被引：162
|
作者：
Li, Wei [1 ]
Xie, Jian-Hua
Lin, Han
Zhou, Qi-Lin
机构：
[1] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China
来源：
GREEN CHEMISTRY | 2012年 / 14卷 / 09期
基金：
中国国家自然科学基金;
关键词：
PHOSPHINE COMPLEXES; CONVERSION; CHEMICALS; RUTHENIUM; ALCOHOLS; ESTERS; FUELS; BIOFUELS; LIQUID; MILD;
D O I：
10.1039/c2gc35650c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A highly efficient catalytic method for hydrogenation of biomass-derived levulinic acid has been developed and the iridium trihydride complexes of PNP pincer ligands were found to be extremely active catalysts for this transformation, providing gamma-valerolactone in high yields with TONs as high as 71 000.
引用
收藏
页码：2388 / 2390
页数：3
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