Chiral hydrogen-bonded supramolecular capsules: synthesis, characterization and complexation of C70

被引:12
|
作者
Kohlhaas, Martha [1 ,2 ]
Zaehres, Manfred [2 ,3 ]
Mayer, Christian [2 ,3 ]
Engeser, Marianne [4 ]
Merten, Christian [5 ]
Niemeyer, Jochen [1 ,2 ]
机构
[1] Univ Duisburg Essen, Inst Organ Chem, Univ Str 7, D-45141 Essen, Germany
[2] Univ Duisburg Essen, Ctr Nanointegrat Duisburg Essen CENIDE, Univ Str 7, D-45141 Essen, Germany
[3] Univ Duisburg Essen, Dept Phys Chem, D-45141 Essen, Germany
[4] Univ Bonn, Kekule Inst Organ Chem & Biochem, Gerhard Domagk Str 1, D-53121 Bonn, Germany
[5] Ruhr Univ Bochum, Organ Chem 2, Univ Str 150, D-44801 Bochum, Germany
关键词
MOLECULAR RECOGNITION; HOSTS; MULTICOMPONENT; ENCAPSULATION; SOFTBALLS; CATALYSIS; POLAR;
D O I
10.1039/c8cc10152c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two supramolecular nanocapsules were generated by multi-component self-assembly of the novel bisphosphoric acid (R,R)-6 with suitable bis- and trisamidines. The resulting chiral, hydrogen-bonded capsules are stable even in polar media and at low concentrations and can be employed for the binding of C-70-fullerene in solution.
引用
收藏
页码:3298 / 3301
页数:4
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