SELECTION OF A BINDER FOR A ZEOLITE-CONTAINING CRACKING CATALYST ON AL-PILLARED TAGAN MONTMORILLONITE

被引:1
|
作者
Zakarina, Na. [1 ,2 ,3 ]
Akurpekova, A. K. [1 ,3 ]
Kornaukhova, Na. [1 ,3 ]
Dalelkhanuly, O. [3 ]
机构
[1] JCS DV Sokolsky Inst Fuel Catalysis & Electrochem, Chem Sci, Alma Ata, Kazakhstan
[2] JCS DV Sokolsky Inst Fuel Catalysis & Electrochem, Alma Ata, Kazakhstan
[3] JCS DV Sokolsky Inst Fuel Catalysis & Electrochem, Lab Oil Proc Catalysts, Alma Ata, Kazakhstan
关键词
catalytic cracking; montmorillonite; strength; gasoline; zeolite; vacuum gas oil (VG);
D O I
10.32014/2020.2518-170X.70
中图分类号
P [天文学、地球科学];
学科分类号
07 ;
摘要
It was shown that the strength of Al(2.5) NaHMM + HLaY + NaMM catalysts increases significantly with the introduction of NaMM. The optimal amount of NaMM additive is 10 mass%. With an increase in the calcination temperature of this catalyst, an increase in strength is observed, which reaches a maximum value (223.4 N/sm(2)) at 600 degrees C. A further increase in the amount of introduced NaMM to 15 and 20 wt.% reduces the strength of the catalysts at all studied calcination temperatures. On Al (2.5) NaHMM + HLaY + NaMM catalyst, a large amount (42.5%) of gaseous hydrocarbons is formed at 500 degrees C, which decreases with an increase in cracking temperature to 550 degrees C. The gasoline yield at 500 degrees C is 42.0%, light gas oil 5.5%. With an increase in cracking temperature, the yield of gasoline decreases to 39.5%, and light gas oil increases to 15.8%. Under these conditions, a decrease in the yield of gaseous hydrocarbons to 28.8% is observed. Comparison of the results of VG cracking on catalysts with and without NaMM binder showed that the introduction of NaMM does not significantly affect the yield of gasoline.
引用
收藏
页码:182 / 185
页数:4
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