Solvothermal synthesis of chromium(III) complexes with the 'Bis-tris' ligand

被引：3

作者：

Graham, Kristoffer ^{[1
]}

Sharp, Laura E. ^{[1
]}

Thomas, Lynne H. ^{[2
]}

Murrie, Mark ^{[1
]}

机构：

[1] Univ Glasgow, Sch Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland

[2] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 25卷

基金：

英国工程与自然科学研究理事会;

关键词：

Chromium(III); Polydentate ligands; Solvothermal; Crystal structure; Magnetic properties; STRUCTURAL-CHARACTERIZATION; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURE; CARBOXYLATES; CLUSTER; IRON(III);

D O I：

10.1016/j.inoche.2012.08.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In methanol under solvothermal conditions, we show how the nuclearity of the complex can be tuned from a monomer [Cr-III(H3L)Cl] (1) to a tetramer [Cr-4(III)(H2L)(4)] (2) with an unusual twisted {M4O4} core topology {Bis-tris, H5L=(HOCH2CH2)(2)NC(CH2OH)(3)}. The magnetic data for 2 can be fitted to a simple 1J model with J=-20.25(5)cm(-1). (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：89 / 91

页数：3

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