Assessment of the molecular structure of the borate mineral boracite Mg3B7O13Cl using vibrational spectroscopy

被引：5

作者：

Frost, Ray L. ^{[1
]}

Xi, Yunfei ^{[1
]}

Scholz, Ricardo ^{[2
]}

机构：

[1] Queensland Univ Technol, Fac Sci & Engn, Sch Chem Phys & Mech Engn, Brisbane, Qld 4001, Australia

[2] Univ Fed Ouro Preto, Sch Mines, Dept Geol, BR-3540000 Ouro Preto, MG, Brazil

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2012年 / 96卷

基金：

澳大利亚研究理事会;

关键词：

Raman spectroscopy; Borate; Boracite; Infrared; Evaporite; FERROELECTRIC PHASE-TRANSITION; CHLORINE BORACITE; CRYSTAL-STRUCTURE; RAMAN-SPECTRUM; FT-IR; INFRARED-SPECTRA; GLASSES; DOMAINS; LEAD; EPR;

D O I：

10.1016/j.saa.2012.07.115

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Boracite is a magnesium borate mineral with formula: Mg3B7O13Cl and occurs as blue green, colorless, gray, yellow to white crystals in the orthorhombic - pyramidal crystal system. An intense Raman band at 1009 cm(-1) was assigned to the BO stretching vibration of the B7O13 units. Raman bands at 1121, 1136, 1143 cm(-1) are attributed to the in-plane bending vibrations of trigonal boron. Four sharp Raman bands observed at 415, 494, 621 and 671 cm(-1) are simply defined as trigonal and tetrahedral borate bending modes. The Raman spectrum clearly shows intense Raman bands at 3405 and 3494 cm(-1), thus indicating that some Cl anions have been replaced with OH units. The molecular structure of a natural boracite has been assessed by using vibrational spectroscopy. (c) 2012 Elsevier B.V. All rights reserved.

引用

页码：946 / 951

页数：6

共 50 条

[21] SPONTANEOUS BIREFRINGENCE AND POLARIZATION STUDIES ON BORACITE CR3B7O13CL
YE, ZG
RIVERA, JP
BURKHARDT, E
SCHMID, H
PHASE TRANSITIONS, 1991, 37 (01) : 13 - 26
[22] A Novel Blue-Emitting Phosphor of Eu2+-Activated Magnesium Haloborate Mg3B7O13Cl
Qiao, Xuebin
Seo, Hyo Jin
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2015, 98 (02) : 594 - 600
[23] STRUCTURE OF THE FULLY FERROELECTRIC FULLY FERROELASTIC ORTHORHOMBIC ROOM-TEMPERATURE PHASE OF COBALT BROMINE BORACITE, CO3B7O13BR AND NICKEL CHLORINE BORACITE, NI3B7O13CL
KUBEL, F
MAO, SY
SCHMID, H
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 : 1167 - 1170
[24] Crystal structure of manganese bromine boracite, Mn3B7O13Br
Kubel, F
Crottaz, O
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1996, 211 (12): : 925 - 925
[25] Crystal structure of manganese iodine boracite, Mn3B7O13I
Kubel, F
Crottaz, O
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1996, 211 (12): : 926 - 926
[26] Zn3B7O13Cl: A New Deep-Ultraviolet Transparency Nonlinear Optical Crystal with Boracite Structure
Xiong, Zheyao
He, Jiangang
Hu, Bing
Shan, Pai
Wang, Zujian
Su, Rongbing
He, Chao
Yang, Xiaoming
Long, Xifa
ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (38) : 42942 - 42948
[27] Vibrational spectroscopy of the borate mineral kotoite Mg3(BO3)2
Frost, Ray L.
Xi, Yunfei
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2013, 103 : 151 - 155
[28] CHARACTERIZATION OF THE BORACITE CU3B7O13BR
BERSET, G
CLIN, M
RIVERA, JP
SCHMID, H
HELVETICA PHYSICA ACTA, 1987, 60 (02): : 315 - 315
[29] Effects of mechanical stress on the domain structure and phase coexistence in the boracite Cr3B7O13Cl single crystals
Topolov, VY
Ye, ZG
FERROELECTRICS, 1999, 221 (1-4) : 117 - +
[30] Calorimetric, optical and electron microscopy studies of Co3B7O13Cl ferroic boracite
Castellanos-Guzman, AG
Czank, M
Kumar, A
Singh, G
Tiwari, VS
Wadhawan, VK
FERROELECTRICS, 2001, 251 (1-4) : 61 - 68

← 1 2 3 4 5 →