Palladium-Based Anion- Exchange Membrane Fuel Cell Using KOH- Doped Polybenzimidazole as the Electrolyte

被引：18
|
作者：
Fujigaya, Tsuyohiko [1 ,2 ]
Kim, ChaeRin [1 ]
Matsumoto, Kazuya [1 ]
Nakashima, Naotoshi [1 ,2 ,3 ]
机构：
[1] Kyushu Univ, Grad Sch Engn, Dept Appl Chem, Nishi Ku, Fukuoka 8190395, Japan
[2] Kyushu Univ, World Premier Int WPI Res Ctr, Int Inst Carbon Neutral Energy Res I2CNER, Nishi Ku, Fukuoka 8190395, Japan
[3] JST CREST, Chiyoda Ku, Tokyo 1020075, Japan
来源：
CHEMPLUSCHEM | 2014年 / 79卷 / 03期
关键词：
fuel cells; ion exchange; nanotubes; oxygen reduction reaction; palladium; OXYGEN REDUCTION REACTION; ALKALINE POLYMER ELECTROLYTE; CARBON NANOTUBES; CONDUCTING MEMBRANES; PD NANOPARTICLES; HIGH-TEMPERATURE; CATALYSTS; ELECTROCATALYST; ELECTROREDUCTION; PERFORMANCE;
D O I：
10.1002/cplu.201300377
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The development of a low-cost and high-performance fuel cell is a strong social demand. Anion-exchange membrane fuel cells (AEMFCs) have recently emerged as an alternative technology to conventional fuel cells that use a proton-exchange membrane as they enable the use of cheaper metals than platinum. An AEMFC exhibiting a maximum power density of 241mWcm(-2) based on a palladium-based electrocatalyst has been developed. The polybenzimidazole-wrapped carbon nanotubes were used to anchor the palladium nanoparticles, and the material was doped using KOH to form an ideal triple-phase boundary structure around the palladium. The observed maximum power density is the highest among previously reported AEMFCs using palladium as the metal catalyst.
引用
收藏
页码：400 / 405
页数：6
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