Esterification of Salicylic Acid with Dimethyl Carbonate over Mesoporous Aluminosilicate

被引：21

作者：

Su, Xiaowei ^{[1
,2
]}

Li, Junping ^{[1
]}

Xiao, Fukui ^{[1
]}

Wei, Wei ^{[1
]}

Sun, Yuhan ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2009年 / 48卷 / 07期

关键词：

BENIGN BUILDING-BLOCK; CARBOXYLIC-ACIDS; O-METHYLATION; ZEOLITES; PHENOLS; DMC; CARBOMETHOXYLATION; ALKYLATION; CATALYSIS; ESTERS;

D O I：

10.1021/ie801148v

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The synthesis of methyl salicylate (MS) from salicylic acid (SA) and dimethyl carbonate (DMC) was performed over a series of mesoporous aluminosilicates. The results showed that mesoporous aluminosilicate was an effective esterification catalyst for the reaction. It was also found that both SA conversion and MS selectivity were closely linked with the intermediate strong acidity and Lewis acidity of catalysts. As a result, the synergistic mechanism was proposed for the esterification of SA with DMC over a mesoporous aluminosilicate.

引用

页码：3685 / 3691

页数：7

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