Densities, Viscosities, Speeds of Sound, and Refractive Indices of Binary Mixtures of 2-Ethyl-1-hexanol with Benzene and Halobenzenes

被引:14
|
作者
Bhatia, Subhash C. [1 ]
Sangwan, Jasbir [1 ]
Rani, Ruman [1 ]
Kiran, Vijay [1 ]
机构
[1] Kurukshetra Univ, Dept Chem, Kurukshetra 136119, Haryana, India
关键词
Chlorobenzenes; Density; 2-Ethyl-1-hexanol; Excess molar volume; Molar refraction; Refractive index; Speed of sound; Viscosity;
D O I
10.1007/s10765-013-1526-8
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities, , viscosities, , speeds of sound, , and refractive indices, , of binary liquid mixtures of 2-ethyl-1-hexanol with benzene, chlorobenzene, and bromobenzene have been measured over the entire range of composition at 298.15 K, 303.15 K, and 308.15 K and at atmospheric pressure. From the experimental data of the density, speed of sound, viscosity, and refractive index, the values of the excess molar volume, , isentropic compressibility, , and deviations in molar refraction, , have been calculated. The viscosity data have been correlated using McAllister's three-body interaction model at different temperatures. The calculated excess and deviation functions have been analyzed in terms of molecular interactions and structural effects.
引用
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页码:2076 / 2088
页数:13
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